All-metal aromaticity and antiaromaticity

被引：527

作者：

Boldyrev, AI ^{[1
]}

Wang, LS

机构：

[1] Utah State Univ, Dept Chem & Biochem, Logan, UT 84322 USA

[2] Washington State Univ, Dept Phys, Richland, WA 99354 USA

[3] Pacific NW Natl Lab, WR Wiley Environm Mol Sci Lab, Richland, WA 99354 USA

[4] Pacific NW Natl Lab, Div Chem Sci, Richland, WA 99354 USA

来源：

CHEMICAL REVIEWS | 2005年 / 105卷 / 10期

关键词：

D O I：

10.1021/cr030091t

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

All-metal aromatic/antiaromatic clusters tackled are gaseous species and had undergone photoelectron spectroscopy (PES) including Li, Na and Cu. In 2001, aromaticity has been found in large number of new gaseous all-metal or metalloid clusters extending its way to metal alloys. Experimental and theoretical characterization of an all-metal cluster with conflicting aromaticity, Al4, in the Li3Al4 bimetallic clusters. New developments in aromaticity and antiaromaticity in all-metal or metalloid cluster systems are important for developing a unified chemical bonding theory throughout chemistry.

引用

页码：3716 / 3757

页数：42

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