Absolute stereochemistry of TT-1 (rasfonin), an α-pyrone-containing natural product from a fungus, Trichurus terrophilus

被引：15

作者：

Akiyama, K ^{[1
]}

Kawamoto, S ^{[1
]}

Fujimoto, H ^{[1
]}

Ishibashi, M ^{[1
]}

机构：

[1] Chiba Univ, Grad Sch Pharmaceut Sci, Inage Ku, Chiba 2638522, Japan

来源：

TETRAHEDRON LETTERS | 2003年 / 44卷 / 46期

关键词：

D O I：

10.1016/j.tetlet.2003.09.136

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The absolute stereochemistry of TT-1 (1 =rasfonin), an alpha-pyrone-containing natural product from a Fungi Imperfecti, Trichurus terrophilus, was determined as 5R,6R,7S,9R, and 6'S on the basis of synthesis of diastereomers of two fragments of 1 in optically active forms, and comparison of their spectral and optical data with those of natural specimens. (C) 2003 Elsevier Ltd. All rights reserved.

引用

页码：8427 / 8431

页数：5

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