Studies on the stereochemistry of theonezolides A-C1:: Elucidation of the relative configurations of 1,3-diol moieties of the C-4∼C-17 fragment

被引:5
作者
Kobayashi, J [1 ]
Yonezawa, M [1 ]
Takeuchi, S [1 ]
Ishibashi, M [1 ]
机构
[1] Hokkaido Univ, Fac Pharmaceut Sci, Sapporo, Hokkaido 0600812, Japan
关键词
D O I
10.3987/COM-97-S6-1
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Four model compounds having syn and anti 1,3-diol type moieties corresponding to C-8/C-10 and C-14/C-16 positions contained in the C-4 similar to C-17 fragment of theonezolides A-C were prepared. Comparison of their spectral data suggested that the 1,3-diol at C-8/C-10 and the OH/OMe groups at C-14/C-16 positions of theonezolides A-C were both syn.
引用
收藏
页码:39 / 42
页数:4
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