Aerosol-assisted rapid synthesis of SnS-C composite microspheres as anode material for Na-ion batteries

被引:110
作者
Choi, Seung Ho [1 ]
Kang, Yun Chan [1 ]
机构
[1] Korea Univ, Dept Mat Sci & Engn, Seoul 136713, South Korea
基金
新加坡国家研究基金会;
关键词
tin sulfide; anode material; carbon composite; sodium battery; energy storage; HIGH-CAPACITY ANODE; LITHIUM-ION; LI-ION; ELECTROCHEMICAL PROPERTIES; METAL-OXIDE; SODIUM; STORAGE; PERFORMANCE; SULFIDE; NANOCOMPOSITES;
D O I
10.1007/s12274-014-0648-z
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
SnS-C composite powders were prepared through one-pot spray pyrolysis for use as anode materials for Na-ion batteries. C microspheres with uniformly attached cubic-like SnS nanocrystals, which have an amorphous C coating layer, were formed at a preparation temperature of 900 A degrees C. The initial discharge capacities of the bare SnS and SnS-C composite powders at a current density of 500 mA center dot g(-1) were 695 and 740 mA center dot h center dot g(-1), respectively. The discharge capacities after 50 cycles and the capacity retentions measured from the second cycle of the bare SnS and SnS-C composite powders were 25 and 433 mA center dot h center dot g(-1) and 5 and 89%, respectively. The prepared SnS-C composite powders with high reversible capacities and good cycle performance can be used as Na-ion battery anode materials.
引用
收藏
页码:1595 / 1603
页数:9
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