Hexanuclear manganese(III) single-molecule magnets

被引：238

作者：

Milios, CJ

Raptopoulou, CP

Terzis, A

Lloret, F

Vicente, R

Perlepes, SP ^{[1
]}

Escuer, A

机构：

[1] Univ Patras, Dept Chem, Patras 26500, Greece

[2] Univ Barcelona, Dept Quim Inorgan, E-08028 Barcelona, Spain

[3] NCSR Demokritos, Inst Mat Sci, Aghia Paraskevi 15310, Greece

[4] Univ Valencia, Dept Quim Inorgan, E-46100 Burjassot, Spain

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2004年 / 43卷 / 02期

关键词：

cluster compounds; magnetic properties; manganese; N; O ligands; single-molecule magnets;

D O I：

10.1002/anie.200351079

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Clusters of magnets: The first examples of manganese single-molecule magnets (SMMs) consisting exclusively of trivalent metal centers are reported. These are hexanuclear clusters containing the [MnIII 6(μ3-O)2(μ2-OR) 2]12+ core (see picture, Mn yellow, O red) and have an S= 4 ground state. Variation of the oxygen-containing ligands allows a potentially large family of SMMs to be prepared.

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页码：210 / 212

页数：3

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