A High-Efficiency Panchromatic Squaraine Sensitizer for Dye-Sensitized Solar Cells

被引:137
作者
Shi, Yanrong [2 ,3 ]
Hill, Rebecca B. M. [1 ]
Yum, Jun-Ho [1 ]
Dualeh, Amalie [1 ]
Barlow, Stephen [2 ,3 ]
Graetzel, Michael [1 ]
Marder, Seth R. [2 ,3 ]
Nazeeruddin, Mohammad K. [1 ]
机构
[1] Swiss Fed Inst Technol, Sch Basic Sci, Inst Chem Sci & Engn, Lab Photon & Interfaces, CH-1015 Lausanne, Switzerland
[2] Georgia Inst Technol, Ctr Organ Photon & Elect, Atlanta, GA 30332 USA
[3] Georgia Inst Technol, Dept Chem & Biochem, Atlanta, GA 30332 USA
关键词
dyes/pigments; light harvesting; sensitizers; solar cells; squaraines; FILMS;
D O I
10.1002/anie.201101362
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Squarely efficient: A squaraine sensitizer (see picture) shows an outstanding power conversion efficiency of 6.74% in liquid dye-sensitized solar cells and 2.69% in solid-state dye-sensitized solar cells. The high efficiencies are related to both the bathochromic shift of the absorption maximum compared to other squaraine sensitizers, and to the presence of additional absorptions that lead to high absorptivity over much of the visible spectrum. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码:6619 / 6621
页数:3
相关论文
共 21 条
[1]  
[Anonymous], 1982, Handbook of Physicsand Chemistry, V63rd
[2]   Squaraine Compounds: Tailored Design and Synthesis towards a Variety of Material Science Applications [J].
Beverina, Luca ;
Salice, Patrizio .
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2010, 2010 (07) :1207-1225
[3]   Panchromatic Cross-Substituted Squaraines for Dye-Sensitized Solar Cell Applications [J].
Beverina, Luca ;
Ruffo, Riccardo ;
Mari, Claudio Maria ;
Pagani, Giorgio A. ;
Sassi, Mauro ;
De Angelis, Filippo ;
Fantacci, Simona ;
Yum, Jun-Ho ;
Graetzel, Michael ;
Nazeeruddin, Mohammad K. .
CHEMSUSCHEM, 2009, 2 (07) :621-624
[4]   Dye-Sensitized Solar Cells with a High Absorptivity Ruthenium Sensitizer Featuring a 2-(Hexylthio)thiophene Conjugated Bipyridine [J].
Cao, Yiming ;
Bai, Yu ;
Yu, Qingjiang ;
Cheng, Yueming ;
Liu, Shi ;
Shi, Dong ;
Gao, Feifei ;
Wang, Peng .
JOURNAL OF PHYSICAL CHEMISTRY C, 2009, 113 (15) :6290-6297
[5]   Chemical redox agents for organometallic chemistry [J].
Connelly, NG ;
Geiger, WE .
CHEMICAL REVIEWS, 1996, 96 (02) :877-910
[6]  
FUHRMANN G, 2009, Patent No. 2009053107
[7]   Molecular Design of Unsymmetrical Squaraine Dyes for High Efficiency Conversion of Low Energy Photons into Electrons Using TiO2 Nanocrystalline Films [J].
Geiger, Thomas ;
Kuster, Simon ;
Yum, Jun-Ho ;
Moon, Soo-Jin ;
Nazeeruddin, Mohammad K. ;
Graetzel, Michael ;
Nueesch, Frank .
ADVANCED FUNCTIONAL MATERIALS, 2009, 19 (17) :2720-2727
[8]   LIGHT-INDUCED REDOX REACTIONS IN NANOCRYSTALLINE SYSTEMS [J].
HAGFELDT, A ;
GRATZEL, M .
CHEMICAL REVIEWS, 1995, 95 (01) :49-68
[9]   Dye-Sensitized Solar Cells [J].
Hagfeldt, Anders ;
Boschloo, Gerrit ;
Sun, Licheng ;
Kloo, Lars ;
Pettersson, Henrik .
CHEMICAL REVIEWS, 2010, 110 (11) :6595-6663
[10]   Unsymmetrical Squaraines Incorporating the Thiophene Unit for Panchromatic Dye-Sensitized Solar Cells [J].
Li, Jheng-Ying ;
Chen, Chia-Yuan ;
Lee, Chuan-Pei ;
Chen, Szu-Chien ;
Lin, Tsu-Han ;
Tsai, Hui-Hsu ;
Ho, Kuo-Chuan ;
Wu, Chun-Guey .
ORGANIC LETTERS, 2010, 12 (23) :5454-5457