Electronic excited-state engineering

被引：34

作者：

Armaroli, Nicola ^{[1
]}

机构：

[1] CNR, Ist Sintesi Organ & Fotoreattivita, Mol Photosci Grp, I-40129 Bologna, Italy

来源：

CHEMPHYSCHEM | 2008年 / 9卷 / 03期

关键词：

arene ligands; copper complexes; electron transfer; excited state equilibration; polypyridines;

D O I：

10.1002/cphc.200700794

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

(Figure Presented) Long-living complexes: A Cu1- bisphenanthroline complex exhibits a 15-fold prolongation of its excited state lifetime due to the planned intervention of an appended anthracene fragment (see picture). This elegant example of electronic excited-state engineering extends the range of possibilities for improving the photophysical properties of Cu 1 complexes. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：371 / 373

页数：3

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