A ruthenium(II) tris(2,2′-bipyridine) derivative possessing a triplet lifetime of 42 μs

被引：121

作者：

Harriman, A ^{[1
]}

Hissler, M ^{[1
]}

Khatyr, A ^{[1
]}

Ziessel, R ^{[1
]}

机构：

[1] Univ Strasbourg, Ecole Europeenne Chim Polymeres & Mat, Lab Chim Elect & Photon Mol, CNRS,UPRESA 7008, F-67087 Strasbourg 2, France

来源：

CHEMICAL COMMUNICATIONS | 1999年 / 08期

关键词：

D O I：

10.1039/a900962k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Grafting an ethynylated-pyrene moiety to a Rn(II) or Os(II) polypyridine complex perturbs the photophysical properties of the metal fragment and, when the relevant energy levels are properly balanced, provides a 115-fold prolongation of the triplet lifetime.

引用

页码：735 / 736

页数：2

共 11 条

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