A five coordinate PdII complex stable in solution and in the solid state

被引：48

作者：

Bröring, M ^{[1
]}

Brandt, CD ^{[1
]}

机构：

[1] Univ Marburg, Fachbereich Chem, D-35043 Marburg, Germany

来源：

CHEMICAL COMMUNICATIONS | 2003年 / 17期

关键词：

D O I：

10.1039/b305547g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The treatment of the strained complex TrpyPdOAc(F) 1 with NaBArF, followed by the addition of trimethylphosphine, yields the stable cationic 16VE- or 18VE-complexes 3 and 4, depending on the amount of phosphane added.

引用

页码：2156 / 2157

页数：2

共 12 条

[1] Anionic Pd(0) and Pd(II) intermediates in palladium-catalyzed Heck and cross-coupling reactions
Amatore, C
Jutand, A
[J]. ACCOUNTS OF CHEMICAL RESEARCH, 2000, 33 (05) : 314 - 321
[2] [(3,5-(CF3)2C6H3)4B]-[H(OET2)2]+ - A CONVENIENT REAGENT FOR GENERATION AND STABILIZATION OF CATIONIC, HIGHLY ELECTROPHILIC ORGANOMETALLIC COMPLEXES
BROOKHART, M
GRANT, B
VOLPE, AF
[J]. ORGANOMETALLICS, 1992, 11 (11) : 3920 - 3922
[3] One compound, two structures:: synthesis, structures and reactivity of a novel (tripyrrinato)palladium(II) trifluoracetate complex TrpyPdOAcf
Bröring, M
Brandt, CD
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2002, (07): : 1391 - 1395
[4] Synthetic and structural studies on metal complexes of tripyrrin
Bröring, M
Brandt, CD
Prikhodovski, S
[J]. JOURNAL OF PORPHYRINS AND PHTHALOCYANINES, 2003, 7 (01) : 17 - 24
[5] Tripyrrin -: the missing link in the series of oligopyrrolic ligands
Bröring, M
Brandt, CD
[J]. CHEMICAL COMMUNICATIONS, 2001, (05) : 499 - 500
[6] Collman J.P., 1987, PRINCIPLES APPL ORGA
[7] Elschenbroich C., 2003, ORGANOMETALLCHEMIE
[8] Crystal structures of palladium(II) and copper(II) complexes of meso-phenyl tripyrrinone
Furuta, H
Maeda, H
Osuka, A
[J]. INORGANIC CHEMISTRY COMMUNICATIONS, 2003, 6 (02) : 162 - 164
[9] JAUMA A, 1996, MONATSH CHEM, V127, P936
[10] Contracted and expanded meso-alkynyl porphyrinoids:: from triphyrin to hexaphyrin
Krivokapic, A
Cowley, AR
Anderson, HL
[J]. JOURNAL OF ORGANIC CHEMISTRY, 2003, 68 (03) : 1089 - 1096

← 1 2 →