Stemocurtisine, the first pyrido[1,2-a]azapine Stemona alkaloid

被引：52

作者：

Mungkornasawakul, P

Pyne, SG ^{[1
]}

Jatisatienr, A

Supyen, D

Lie, W

Ung, AT

Skelton, BW

White, AH

机构：

[1] Univ Wollongong, Dept Chem, Wollongong, NSW 2522, Australia

[2] Chiang Mai Univ, Div Environm Sci, Chiang Mai 50202, Thailand

[3] Chiang Mai Univ, Dept Chem, Chiang Mai 50202, Thailand

[4] Univ Western Australia, Dept Chem, Crawley, WA 6009, Australia

来源：

JOURNAL OF NATURAL PRODUCTS | 2003年 / 66卷 / 07期

关键词：

D O I：

10.1021/np020612s

中图分类号：

Q94 [植物学];

学科分类号：

071001 ;

摘要：

A new pentacyclic stemona alkaloid, stemocurtisine (2), with a novel pyrido[1,2-a]azapine A,B-ring system, has been isolated from a root extract of Stemona curtisii. The structure and relative stereochemistry was determined by spectral data interpretation and X-ray crystallography.

引用

页码：980 / 982

页数：3

共 22 条

[1] Feeding deterrence and contact toxicity of Stemona alkaloids -: A source of potent natural insecticides [J].

Brem, B ;

Seger, C ;

Pacher, T ;

Hofer, O ;

Vajrodaya, S ;

Greger, H .

JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY, 2002, 50 (22) :6383-6388

[2]

CRONQUIST A, 1981, INTEGRATED SYSTEM CL, P1224

[3]

IRIE H, 1973, CHEM PHARM BULL, V21, P451

[4] STRUCTURE OF ALKALOID PROTOSTEMONINE [J].

IRIE, H ;

HARADA, H ;

OHNO, K ;

MIZUTANI, T ;

UYEO, S .

JOURNAL OF THE CHEMICAL SOCIETY D-CHEMICAL COMMUNICATIONS, 1970, (05) :268-&

[5] CRYSTAL STRUCTURE OF A NEW ALKALOID, STEMOFOLINE, FROM STEMONA-JAPONICA [J].

IRIE, H ;

MASAKI, N ;

OHNO, K ;

OSAKI, K ;

TAGA, T ;

UYEO, S .

JOURNAL OF THE CHEMICAL SOCIETY D-CHEMICAL COMMUNICATIONS, 1970, (17) :1066-&

[6] Isolation and stereochemistry of two new alkaloids from Stemona tuberosa [J].

Jiang, RW ;

Hon, PM ;

But, PPH ;

Chung, HS ;

Lin, G ;

Ye, WC ;

Mak, TCW .

TETRAHEDRON, 2002, 58 (33) :6705-6712

[7] Occurrence of the insecticidal 16,17-didehydro-16(E)-stemofoline in Stemona collinsae [J].

Jiwajinda, S ;

Hirai, N ;

Watanabe, K ;

Santisopasri, V ;

Chuengsamarnyart, N ;

Koshimizu, K ;

Ohigashi, H .

PHYTOCHEMISTRY, 2001, 56 (07) :693-695

[8]

PHANURAI P, 1977, B DEP MED SCI, V19, P217

[9] Recent progress in the chemistry of the Stemona alkaloids [J].

Pilli, RA ;

de Oliveira, MDCF .

NATURAL PRODUCT REPORTS, 2000, 17 (01) :117-127

[10]

PRUCKSUNAND C, 1985, J MED ASSOC THAILAND, V68, P66

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