Synthesis and characterisation of nanoporous carbide-derived carbon by chlorination of vanadium carbide

被引：113

作者：

Janes, Alar ^{[1
]}

Thomberg, Thomas ^{[1
]}

Lust, Enn ^{[1
]}

机构：

[1] Univ Tartu, Inst Phys Chem, EE-51014 Tartu, Estonia

来源：

CARBON | 2007年 / 45卷 / 14期

关键词：

D O I：

10.1016/j.carbon.2007.09.041

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Nanoporous carbide-derived carbon (CDC) was synthesised from vanadium carbide (VC) powder via gas phase chlorination in the temperature range from 500 to 1100 degrees C. The XRD analysis of nanoporous carbon powder samples was carried out to investigate the structural changes (graphitisation) of nanoporous carbons synthesised. The first-order Raman spectra showed the absorption peak at similar to 1582 cm(-1) and the disorder-induced (D) peak at similar to 1345 cm(-1). The low-temperature N-2 adsorption experiments were performed and a specific surface area up to 1305 m(2) g(-1) and total pore volume up to 0.66 cm(3) g(-1) were obtained. (C) 2007 Elsevier Ltd. All rights reserved.

引用

页码：2717 / 2722

页数：6

共 29 条

[21] Characterization of nanoporous materials from adsorption and desorption isotherms [J].