Comparison of different porous sol-gel matrices: template synthesis of polythiophene

被引:15
作者
Ballarin, B
Facchini, M
Dal Pozzo, L
Martini, C
机构
[1] Univ Bologna, Dipartimento Chim Fis & Inorgan, I-40136 Bologna, Italy
[2] Univ Bologna, Dipartimento Chim Ind & Mat, I-40136 Bologna, Italy
[3] Univ Bologna, Ist Met, I-40136 Bologna, Italy
关键词
composite; template; polythiophene; sol-gel; hybrid organic inorganic materials; conducting polymer;
D O I
10.1016/S1388-2481(03)00145-0
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Composite using polythiophene as the conducting polymer and different silica sol-gel as the host matrix were prepared by the template method. The electrochemical performance of the composites has been confirmed using cyclic voltammetry and was compared with the results obtained on polythiophene films synthetised under the same condition directly on ITO substrates. UV-Vis-NIR spectroscopy, scanning electron and atomic force microscopic measurements were done on all the different composites. (C) 2003 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:625 / 631
页数:7
相关论文
共 17 条
[1]   On the initiation and growth of polymer films onto electrode surfaces [J].
Abrantes, LM ;
Correia, JP .
ELECTROCHIMICA ACTA, 1999, 44 (12) :1901-1910
[2]   Tailored porous materials [J].
Barton, TJ ;
Bull, LM ;
Klemperer, WG ;
Loy, DA ;
McEnaney, B ;
Misono, M ;
Monson, PA ;
Pez, G ;
Scherer, GW ;
Vartuli, JC ;
Yaghi, OM .
CHEMISTRY OF MATERIALS, 1999, 11 (10) :2633-2656
[3]  
BRINKER CJ, 1989, SOL GEL SCI, pCH9
[4]   TEMPLATE SYNTHESIS OF METAL MICROTUBULE ENSEMBLES UTILIZING CHEMICAL, ELECTROCHEMICAL, AND VACUUM DEPOSITION TECHNIQUES [J].
BRUMLIK, CJ ;
MENON, VP ;
MARTIN, CR .
JOURNAL OF MATERIALS RESEARCH, 1994, 9 (05) :1174-1183
[5]  
DALTAMIR JM, 2000, QUIM NOVA, V23, P204
[6]   Template synthesis of polyaniline: A route to achieve nanocomposites [J].
das Neves, S ;
de Torresi, SIC ;
Zoppi, RA .
SYNTHETIC METALS, 1999, 101 (1-3) :754-755
[7]  
DASNEVES S, 2002, J POWER SOURCES, V107, P13
[8]   Thickness, morphology and structure of sol-gel hybrid films: I - The role of the precursor solution's ageing [J].
Fidalgo, A ;
Ilharco, LM .
JOURNAL OF SOL-GEL SCIENCE AND TECHNOLOGY, 2003, 26 (1-3) :363-367
[9]  
GORKY K, 2002, SYNTHETIC MET, V125, P365
[10]  
HEINZE J, 1988, BER BUNSEN PHYS CHEM, V92, P1271