Strategy for constructing photosynthetic models: Porphyrin-containing modules assembled around transition metals

被引：325

作者：

Harriman, A ^{[1
]}

Sauvage, JP ^{[1
]}

机构：

[1] UNIV STRASBOURG 1,FAC CHIM,LAB CHIM ORGANOMINERALE,F-67008 STRASBOURG,FRANCE

来源：

CHEMICAL SOCIETY REVIEWS | 1996年 / 25卷 / 01期

关键词：

D O I：

10.1039/cs9962500041

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Transition metal complexes formed from oligopyridino ligands covalently attached to porphyrin modules have been used to assemble well-defined, photoactive multicomponent arrays. Apart from gathering together porphyrinic components, the metal complex plays an essential role by modulating the degree of electronic coupling between the porphyrins or by direct participation in sequential electron-transfer steps. Several such-systems have been built and investigated by ultrafast transient spectroscopy, allowing critical comparison with the bacterial photosynthetic reaction centre complex.

引用

页码：41 / &

页数：9

共 38 条

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