Strategy for constructing photosynthetic models: Porphyrin-containing modules assembled around transition metals

被引：325

作者：

Harriman, A ^{[1
]}

Sauvage, JP ^{[1
]}

机构：

[1] UNIV STRASBOURG 1,FAC CHIM,LAB CHIM ORGANOMINERALE,F-67008 STRASBOURG,FRANCE

来源：

CHEMICAL SOCIETY REVIEWS | 1996年 / 25卷 / 01期

关键词：

D O I：

10.1039/cs9962500041

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Transition metal complexes formed from oligopyridino ligands covalently attached to porphyrin modules have been used to assemble well-defined, photoactive multicomponent arrays. Apart from gathering together porphyrinic components, the metal complex plays an essential role by modulating the degree of electronic coupling between the porphyrins or by direct participation in sequential electron-transfer steps. Several such-systems have been built and investigated by ultrafast transient spectroscopy, allowing critical comparison with the bacterial photosynthetic reaction centre complex.

引用

页码：41 / &

页数：9

共 38 条

[21] MULTISTEP ELECTRON-TRANSFER IN A PORPHYRIN-RUTHENIUM(II) BIS(TERPYRIDYL)-PORPHYRIN TRIAD
HARRIMAN, A
ODOBEL, F
SAUVAGE, JP
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (12) : 5481 - 5482
[22] INTRAMOLECULAR ELECTRON AND ENERGY-TRANSFER WITHIN A BISPORPHYRIN IN A LOW-TEMPERATURE GLASS
HARRIMAN, A
HEITZ, V
EBERSOLE, M
VANWILLIGEN, H
[J]. JOURNAL OF PHYSICAL CHEMISTRY, 1994, 98 (19) : 4982 - 4989
[23] AN UNSYMMETRICAL GOLD (III) - ZINC (II) OBLIQUE BIS-PORPHYRIN
HEITZ, V
CHARDONNOBLAT, S
SAUVAGE, JP
[J]. TETRAHEDRON LETTERS, 1991, 32 (02) : 197 - 198
[24] A STRUCTURAL BASIS OF LIGHT ENERGY AND ELECTRON-TRANSFER IN BIOLOGY (NOBEL LECTURE)
HUBER, R
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1989, 28 (07): : 848 - 869
[25] ELECTROCHEMICALLY TRIGGERED SWINGING OF A [2]-CATENATE
LIVOREIL, A
DIETRICHBUCHECKER, CO
SAUVAGE, JP
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (20) : 9399 - 9400
[26] FEMTOSECOND SPECTROSCOPY OF ELECTRON-TRANSFER IN THE REACTION CENTER OF THE PHOTOSYNTHETIC BACTERIUM RHODOPSEUDOMONAS-SPHAEROIDES R-26 - DIRECT ELECTRON-TRANSFER FROM THE DIMERIC BACTERIOCHLOROPHYLL PRIMARY DONOR TO THE BACTERIOPHEOPHYTIN ACCEPTOR WITH A TIME CONSTANT 2.8 +/- 0.2 PSEC
MARTIN, JL
BRETON, J
HOFF, AJ
MIGUS, A
ANTONETTI, A
[J]. PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 1986, 83 (04) : 957 - 961
[27] A CHEMICAL APPROACH TOWARD PHOTOSYNTHETIC REACTION CENTER
MARUYAMA, K
OSUKA, A
[J]. PURE AND APPLIED CHEMISTRY, 1990, 62 (08) : 1511 - 1520
[28] ODOBEL F, 1994, NEW J CHEM, V18, P1139
[29] HIGHLY COUPLED 2-COMPONENT SYSTEMS CONSISTING OF PORPHYRINS ATTACHED TO A RHODIUM(III) BIS-TERPYRIDINE COMPLEX
ODOBEL, F
SAUVAGE, JP
HARRIMAN, A
[J]. TETRAHEDRON LETTERS, 1993, 34 (50) : 8113 - 8116
[30] GEOMETRY DEPENDENCE OF INTRAMOLECULAR PHOTOINDUCED ELECTRON-TRANSFER IN SYNTHETIC ZINC FERRIC HYBRID DIPORPHYRINS
OSUKA, A
MARUYAMA, K
MATAGA, N
ASAHI, T
YAMAZAKI, I
TAMAI, N
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (12) : 4958 - 4959

← 1 2 3 4 →