A coordinatively linked Yb metal-organic framework demonstrates high thermal stability and uncommon gas-adsorption selectivity

被引：290

作者：

Ma, Shengqian ^{[1
]}

Wang, Xi-Sen ^{[1
]}

Yuan, Daqiang ^{[1
]}

Zhou, Hong-Cai ^{[1
]}

机构：

[1] Miami Univ, Dept Chem & Biochem, Oxford, OH 45056 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 22期

基金：

美国国家科学基金会;

关键词：

gas adsorption; materials science; microporous materials; organic-inorganic hybrid composites; ytterbium;

D O I：

10.1002/anie.200800312

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) Narrow pores for high selectivity: The ytterbium metal-organic framework PCN-17, which contains coordinatively (through SO 42- ions) linked, doubly interpenetrated (8,3)-nets (see picture), is stable up to 480°C and exhibits selective adsorption of H 2 and O2 over N2 and CO. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：4130 / 4133

页数：4

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