Kinetic separation of hexane isomers by fixed-bed adsorption with a microporous metal-organic framework

被引：170

作者：

Barcia, Patrick S.

Zapata, Fatima

Silva, Jose A. C.

Rodrigues, Alirio E.

Chen, Banglin ^{[1
]}

机构：

[1] Univ Texas Pan Amer, Dept Chem, Edinburg, TX 78541 USA

[2] Inst Politecn Braganca, Escola Super Tecnol & Gestao, P-5301857 Braganca, SP, Portugal

[3] Univ Porto, Lab Separat & React Engn, Dept Engn Quim, P-4200465 Oporto, Portugal

来源：

JOURNAL OF PHYSICAL CHEMISTRY B | 2007年 / 111卷 / 22期

关键词：

D O I：

10.1021/jp0721898

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A three-dimensional microporous metal-organic framework Zn(BDC)(Dabco)(0.5) (BDC = 1,4-benzenedicarboxylate, Dabco = 1,4-diazabicyclo [2,2,2]octane), having two types of intersecting pores to encapsulate linear hexane and to block branched hexanes, and thus exhibiting highly selective sorption with respect to n-hexane, has been successfully applied to the kinetic separation of hexane isomers by fixed-bed adsorption.

引用

页码：6101 / 6103

页数：3

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