Entropy production and phase space volume contraction

被引:87
作者
Daems, D
Nicolis, G
机构
[1] Univ Cambridge, Dept Appl Math & Theoret Phys, Cambridge CB3 9EW, England
[2] Free Univ Brussels, Ctr Nonlinear Phenomena & Complex Syst, B-1050 Brussels, Belgium
来源
PHYSICAL REVIEW E | 1999年 / 59卷 / 04期
关键词
D O I
10.1103/PhysRevE.59.4000
中图分类号
O35 [流体力学]; O53 [等离子体物理学];
学科分类号
070204 ; 080103 ; 080704 ;
摘要
We inquire whether the connection between entropy production and phase space volume contraction rate reported recently for a class of thermostatted systems is an intrinsic property of a wide class of dynamical systems, or the result of the particular algorithm devised for thermostatting a system of interacting particles obeying, in the presence of nonequilibrium constraints, a time-reversible, dissipative dynamics. A nonequilibrium thermodynamics based on the balance equation for information entropy is developed for dissipative dynamical systems subjected, in addition, to a stochastic forcing. This latter accounts for the thermodynamic fluctuations accompanying the reduced description of the thermostat by a dissipative perturbation, for the interaction between the system and the external reservoirs or for perturbations of external origin. Entropy flux and entropy productionlike terms depending on the characteristics of the dynamics in phase space, particularly the rate of phase space volume contraction, are identified. Their connections with irreversible thermodynamics are explored. In particular, for thermostatted systems we find, without invoking an ad hoc conservation law between the system and the reservoir, that information entropy production is related to the opposite of the rate of phase space volume contraction to the second order in the distance from equilibrium.
引用
收藏
页码:4000 / 4006
页数:7
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