Preparation of chiral α-diazophosphonic acid derivatives

被引：17

作者：

Moody, CJ

Morfitt, CN

Slawin, AMZ

机构：

[1] Univ Exeter, Dept Chem, Exeter EX4 4QD, Devon, England

[2] Univ St Andrews, Dept Chem, St Andrews KY16 9ST, Fife, Scotland

来源：

TETRAHEDRON-ASYMMETRY | 2001年 / 12卷 / 11期

关键词：

D O I：

10.1016/S0957-4166(01)00287-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The chiral alpha -diazophosphonic acid derivatives 3. 6 and 8 were prepared from (-)ephedrine and (S,S)-N,N ' -dimethyl-1,2-diaminocyclohexane; preliminary experiments suggest that the chiral auxiliary exerts little influence in the dirhodium(il) acetate catalysed O-H and N-H insertion reactions. (C) 2001 Elsevier Science Ltd. All rights reserved.

引用

页码：1657 / 1661

页数：5

共 17 条

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