Preparation of chiral α-diazophosphonic acid derivatives

被引:17
作者
Moody, CJ
Morfitt, CN
Slawin, AMZ
机构
[1] Univ Exeter, Dept Chem, Exeter EX4 4QD, Devon, England
[2] Univ St Andrews, Dept Chem, St Andrews KY16 9ST, Fife, Scotland
关键词
D O I
10.1016/S0957-4166(01)00287-7
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The chiral alpha -diazophosphonic acid derivatives 3. 6 and 8 were prepared from (-)ephedrine and (S,S)-N,N ' -dimethyl-1,2-diaminocyclohexane; preliminary experiments suggest that the chiral auxiliary exerts little influence in the dirhodium(il) acetate catalysed O-H and N-H insertion reactions. (C) 2001 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:1657 / 1661
页数:5
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