The structural origins of superior performance in sol-gel catalysts

被引：24

作者：

Ciriminna, R

Ilharco, LM

Fidalgo, A

Campestrini, S

Pagliaro, M

机构：

[1] CNR, Ist Studio Mat Nanostrutturati, I-90146 Palermo, Italy

[2] Inst Super Tecn, Ctr Quim Fis Mol, P-1049001 Lisbon, Portugal

[3] Univ Padua, Dipartimento Sci Chim, I-35131 Padua, Italy

来源：

SOFT MATTER | 2005年 / 1卷 / 03期

关键词：

D O I：

10.1039/b506021b

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Why do sol-gel catalysts often show superior performance in terms of selectivity, stability and reactivity? This work is an attempt to provide a rationale which could be used as a predictive tool in the development of novel catalysts for chemical conversions that will be crucial to achieve a more sustainable development.

引用

收藏

页码：231 / 237

页数：7

相关论文

共 36 条

[11] New and ecofriendly options for the production of speciality and fine chemicals [J].

Choudary, BM ;

Kantam, ML ;

Santhi, PL .

CATALYSIS TODAY, 2000, 57 (1-2) :17-32

[12] Dynamic catalysis in aerobic oxidation by sol-gel living materials [J].

Ciriminna, R ;

Campestrini, S ;

Carraro, M ;

Pagliaro, M .

ADVANCED FUNCTIONAL MATERIALS, 2005, 15 (05) :846-850

[13] Catalysis by sol-gels: An advanced technology for organic chemistry [J].

Ciriminna, R ;

Pagliaro, M .

CURRENT ORGANIC CHEMISTRY, 2004, 8 (18) :1851-1862

[14] Fluorinated silica gels doped with TPAP as effective aerobic oxidation catalysts in dense phase carbon dioxide [J].

Ciriminna, R ;

Campestrini, S ;

Pagliaro, M .

ADVANCED SYNTHESIS & CATALYSIS, 2004, 346 (2-3) :231-236

[15] The effects of material properties on the activity of sol-gel entrapped perruthenate under supercritical conditions [J].

Ciriminna, R ;

Campestrini, S ;

Pagliaro, M .

ADVANCED SYNTHESIS & CATALYSIS, 2003, 345 (11) :1261-1267

[16] Tailoring the catalytic performance of sol-gel-encapsulated tetra-n-propylammonium perruthenate (TPAP) in aerobic oxidation of alcohols [J].

Ciriminna, R ;

Pagliaro, M .

CHEMISTRY-A EUROPEAN JOURNAL, 2003, 9 (20) :5067-5073

[17]

Ciriminna R, 2002, ADV SYNTH CATAL, V344, P159, DOI 10.1002/1615-4169(200202)344:2<159::AID-ADSC159>3.0.CO

[18]

2-Q

[19] Homogeneous catalysis - new approaches to catalyst separation, recovery, and recycling [J].

Cole-Hamilton, DJ .

SCIENCE, 2003, 299 (5613) :1702-1706

[20] Distribution of organic groups in silica gels prepared from organo-alkoxysilanes [J].

DeWitte, BM ;

Commers, D ;

Uytterhoeven, JB .

JOURNAL OF NON-CRYSTALLINE SOLIDS, 1996, 202 (1-2) :35-41

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