Organically templated inorganic/organic hybrid materials:: hydrothermal synthesis and structural characterization of [C4H12N2][In2(C2O4)(HPO4)3]•H2O

被引：55

作者：

Huang, YF

Lii, KH ^{[1
]}

机构：

[1] Acad Sinica, Inst Chem, Taipei 115, Taiwan

[2] Natl Cent Univ, Dept Chem, Chungli 320, Taiwan

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1998年 / 24期

关键词：

D O I：

10.1039/a807345g

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The synthesis and characterization of a novel inorganic/organic hybrid material is described; the 3-D framework consists of InO6 octahedra which are linked by inorganic phosphate and organic oxalate anions to generate intersecting tunnels in which piperazinium cations and water molecules reside.

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页码：4085 / 4086

页数：2

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共 18 条

[1] ASSEMBLY OF PORPHYRIN BUILDING-BLOCKS INTO NETWORK STRUCTURES WITH LARGE CHANNELS [J].

ABRAHAMS, BF ;

HOSKINS, BF ;

MICHAIL, DM ;

ROBSON, R .

NATURE, 1994, 369 (6483) :727-729

[2] Synthesis and structural characterization of a novel tin(II) phosphonate, Sn2(O3PCH3)(C2O4) [J].

Adair, B ;

Natarajan, S ;

Cheetham, AK .

JOURNAL OF MATERIALS CHEMISTRY, 1998, 8 (06) :1477-1479

[3] BOND-VALENCE PARAMETERS OBTAINED FROM A SYSTEMATIC ANALYSIS OF THE INORGANIC CRYSTAL-STRUCTURE DATABASE [J].

BROWN, ID ;

ALTERMATT, D .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1985, 41 (AUG) :244-247

[4] Hydrothermal synthesis, structure, and magnetic properties of a novel monodimensional iron phosphate: [FeF(HPO4)(2),N2C3H12,(H2O)(x)] (X approximate to 0.20) (ULM-14) [J].

Cavellec, M ;

Riou, D ;

Greneche, JM ;

Ferey, G .

INORGANIC CHEMISTRY, 1997, 36 (10) :2187-2190

[5] Synthesis and crystal structure of the first organically templated layered indium phosphate [C5H5NH](+)[In(HPO4)(H2PO4)(2)](-) [J].

Chippindale, AM ;

Brech, SJ .

CHEMICAL COMMUNICATIONS, 1996, (24) :2781-2782

[6] A 3-D organically templated mixed valence (Fe2+/Fe3+) iron phosphate with oxide-centered Fe4O(PO4)4 cubes: Hydrothermal synthesis, crystal structure, magnetic susceptibility, and Mossbauer spectroscopy of [H3NCH2CH2NH3](2)[Fe4O(PO4)(4)]center dot H2O [J].

DeBord, JRD ;

Reiff, WM ;

Warren, CJ ;

Haushalter, RC ;

Zubieta, J .

CHEMISTRY OF MATERIALS, 1997, 9 (09) :1994-1998

[7] HYDROTHERMAL SYNTHESIS AND CRYSTAL-STRUCTURE OF H3NCH2CH2NH3[IN2(HPO4)4] - A NOVEL OCTAHEDRAL TETRAHEDRAL FRAMEWORK INDIUM PHOSPHATE WITH OCCLUDED ORGANIC CATIONS [J].

DHINGRA, SS ;

HAUSHALTER, RC .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1993, (21) :1665-1667

[8] SPONTANEOUS ASSEMBLY OF A HINGED COORDINATION NETWORK [J].

GARDNER, GB ;

VENKATARAMAN, D ;

MOORE, JS ;

LEE, S .

NATURE, 1995, 374 (6525) :792-795

[9] Engineering coordination architecture by hydrothermal synthesis; Preparation, X-ray crystal structure and magnetic behaviour of the coordination solid [Mn-3{C6H3(CO2)(3)-1,3,5}(2)] [J].

Gutschke, SOH ;

Molinier, M ;

Powell, AK ;

Winpenny, REP ;

Wood, PT .

CHEMICAL COMMUNICATIONS, 1996, (07) :823-824

[10] REDUCED MOLYBDENUM PHOSPHATES - OCTAHEDRAL TETRAHEDRAL FRAMEWORK SOLIDS WITH TUNNELS, CAGES, AND MICROPORES [J].

HAUSHALTER, RC ;

MUNDI, LA .

CHEMISTRY OF MATERIALS, 1992, 4 (01) :31-48