Do grain boundaries assist S diffusion in polycrystalline CdS/CdTe heterojunctions?

被引:47
作者
Yan, Y [1 ]
Albin, D [1 ]
Al-Jassim, MM [1 ]
机构
[1] Natl Renewable Energy Lab, Golden, CO 80401 USA
关键词
D O I
10.1063/1.1338969
中图分类号
O59 [应用物理学];
学科分类号
摘要
We report on a transmission electron microscopy and energy-dispersive x-ray spectroscopy study of S diffusion in polycrystalline CdS/CdTe heterojunctions. We find that grain boundaries significantly assist S diffusion in the CdTe layer when the CdTe is grown without the presence of oxygen, i.e., the S diffuses more easily along the grain boundaries than in the grains. However, grain boundaries do not enhance the S diffusion in CdTe when it is grown in the presence of oxygen. The reason is likely to be the formation of Cd-O bonds at the grain boundaries, which are resistance to the S diffusion. (C) 2001 American Institute of Physics.
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页码:171 / 173
页数:3
相关论文
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[21]   First-principles calculation of band offsets, optical bowings, and defects in CdS, CdSe, CdTe, and their alloys [J].
Wei, SH ;
Zhang, SB ;
Zunger, A .
JOURNAL OF APPLIED PHYSICS, 2000, 87 (03) :1304-1311