Poly(ruthenium carbonyl spirobifluorenylporphyrin): a new polymer used as a catalytic device for carbene transfer

被引：43

作者：

Poriel, C

Ferrand, Y

le Maux, P

Paul, C

Rault-Berthelot, J ^{[1
]}

Simonneaux, G

机构：

[1] Univ Rennes 1, CNRS, UMR 6510, Lab Electrochim Mol & Macromol, F-35042 Rennes, France

[2] Univ Rennes 1, CNRS, UMR 6509, Lab Chim Organomet & Biol, F-35042 Rennes, France

来源：

CHEMICAL COMMUNICATIONS | 2003年 / 18期

关键词：

D O I：

10.1039/b306021g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Oxidative electropolymerization of tetraspirobifluorenyl. porphyrin ruthenium(II) carbonyl complexes can be used to coat Pt electrodes with polymeric films; after being removed from the electrode, these polymeric materials are able to catalyze the heterogeneous cyclopropanations and 2,3 sigmatropic rearrangements with ethyl diazoacetate.

引用

收藏

页码：2308 / 2309

页数：2

相关论文

共 16 条

[1] IMMOBILIZATION OF METALLOPORPHYRINS IN ELECTROPOLYMERIZED FILMS - DESIGN AND APPLICATIONS [J].

BEDIOUI, F ;

DEVYNCK, J ;

BIEDCHARRETON, C .

ACCOUNTS OF CHEMICAL RESEARCH, 1995, 28 (01) :30-36

[2] Ruthenium and osmium porphyrin carbene complexes: synthesis, structure, and connection to the metal-mediated cyclopropanation of alkenes [J].

Che, CM ;

Huang, JS .

COORDINATION CHEMISTRY REVIEWS, 2002, 231 (1-2) :151-164

[3] ORBITAL SYMMETRY CONTROL IN REARRANGEMENTS OF ALLYLIC SULPHONIUM YLIDES [J].

COSE, RWC ;

DAVIES, AM ;

OLLIS, WD ;

SMITH, C ;

SUTHERLA.IO .

JOURNAL OF THE CHEMICAL SOCIETY D-CHEMICAL COMMUNICATIONS, 1969, (06) :293-&

[4]

CRESTINI C, 2000, PORPHYRIN HDB, V11, P161

[5] Polypyrrole films containing metal complexes: Syntheses and applications [J].

Deronzier, A ;

Moutet, JC .

COORDINATION CHEMISTRY REVIEWS, 1996, 147 :339-371

[6] Asymmetric cyclopropanation of styrene catalyzed by chiral macrocyclic iron(II) complexes [J].

Du, GD ;

Andrioletti, B ;

Rose, E ;

Woo, LK .

ORGANOMETALLICS, 2002, 21 (21) :4490-4495

[7] A novel chiral ruthenium porphyrin as highly efficient and selective catalyst for asymmetric cyclopropanations [J].

Frauenkron, M ;

Berkessel, A .

TETRAHEDRON LETTERS, 1997, 38 (41) :7175-7176

[8] Recoverable catalysts and reagents using recyclable polystyrene-based supports [J].

McNamara, CA ;

Dixon, MJ ;

Bradley, M .

CHEMICAL REVIEWS, 2002, 102 (10) :3275-3299

[9] APPLICATIONS OF THIN-LAYER FTIR, UV-VIS, AND ESR SPECTROELECTROCHEMISTRY FOR EVALUATING (TPP)RU(CO) REDOX REACTIONS IN NONAQUEOUS MEDIA [J].

MU, XH ;

KADISH, KM .

LANGMUIR, 1990, 6 (01) :51-56

[10]

Poriel C, 2003, SYNLETT, P71