High CO2 uptake and selectivity by triptycene-derived benzimidazole-linked polymers

被引：211

作者：

Rabbani, Mohammad Gulam ^{[1
]}

Reich, Thomas E. ^{[1
]}

Kassab, Refaie M. ^{[1
]}

Jackson, Karl T. ^{[1
]}

El-Kaderi, Hani M. ^{[1
]}

机构：

[1] Virginia Commonwealth Univ, Dept Chem, Richmond, VA 23284 USA

来源：

CHEMICAL COMMUNICATIONS | 2012年 / 48卷 / 08期

关键词：

METAL-ORGANIC FRAMEWORKS; CARBON-DIOXIDE; HYDROGEN STORAGE; CAPTURE; NETWORKS; ADSORPTION; POROSITY; BINDING; PORES;

D O I：

10.1039/c2cc16986j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Successful incorporation of triptycene into benzimidazole-linked polymers leads to the highest CO2 uptake (5.12 mmol g(-1), 273 K and 1 bar) by porous organic polymers and results in high CO2/N-2 (63) and CO2/CH4 (8.4) selectivities.

引用

页码：1141 / 1143

页数：3

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