Novel triptycene-derived hosts: synthesis and their applications in supramolecular chemistry

被引：237

作者：

Chen, Chuan-Feng ^{[1
]}

机构：

[1] Chinese Acad Sci, Inst Chem, CAS KeyLab Mol Recognit & Funct, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2011年 / 47卷 / 06期

基金：

中国国家自然科学基金;

关键词：

CYLINDRICAL MACROTRICYCLIC HOST; MOLECULAR TWEEZERS; CONFORMATIONAL CHARACTERISTICS; PARAQUAT DERIVATIVES; CYCLIC POLYETHERS; HIGHLY EFFICIENT; FULLERENES C-60; SQUARAINE DYES; COMPLEXATION; BINDING;

D O I：

10.1039/c0cc04852f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The development of new classes of macrocyclic hosts has always been one of the most important topics in supramolecular chemistry. During the past several years, based on the triptycene with unique three-dimensional rigid structure, several different kinds of novel triptycene-derived hosts including triptycene-derived cylindrical macrotricyclic polyether, triptycene-derived tris(crown ether)s, triptycene-derived molecular tweezers, triptycene-derived calixarenes, triptycene-derived heterocalixarenes, triptycene-derived tetralactam macrocycles and molecular cage have been designed and synthesized. Then, by exploring the applications of some of the triptycene derived hosts in molecular recognition and molecular assemblies, a series of new supramolecular systems with specific structures and properties have been developed. This feature article highlights our recent advances in the synthesis of triptycene-derived hosts and their applications in supramolecular chemistry.

引用

页码：1674 / 1688

页数：15

共 119 条

[1] Metallacyclopeptides: Artificial analogues of naturally occurring peptides [J].

Albrecht, M ;

Stortz, P .

CHEMICAL SOCIETY REVIEWS, 2005, 34 (06) :496-506

[2] MACROPOLYCYCLIC POLYETHERS (CAGES) AND RELATED-COMPOUNDS [J].

AN, HY ;

BRADSHAW, JS ;

IZATT, RM .

CHEMICAL REVIEWS, 1992, 92 (04) :543-572

[3] Squaraine-derived rotaxanes: Sterically protected fluorescent near-IR dyes [J].

Arunkumar, E ;

Forbes, CC ;

Noll, BC ;

Smith, BD .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (10) :3288-3289

[4] DOUBLY ENCIRCLED AND DOUBLE-STRANDED PSEUDOROTAXANES [J].

ASHTON, PR ;

CHRYSTAL, EJT ;

GLINK, PT ;

MENZER, S ;

SCHIAVO, C ;

STODDART, JF ;

TASKER, PA ;

WILLIAMS, DJ .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1995, 34 (17) :1869-1871

[5]

Atwood J.L., 1996, COMPREHENSIVE SUPRAM

[6] The exclusivity of multivalency in dynamic covalent processes [J].

Badjic, JD ;

Cantrill, SJ ;

Grubbs, RH ;

Guidry, EN ;

Orenes, R ;

Stoddart, JF .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (25) :3273-3278

[7] Triptycene (9,10-o-benzenoanthracene [J].

Bartlett, PD ;

Ryan, MJ ;

Cohen, SG .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1942, 64 :2649-2653

[8] Structure and binding properties of water-soluble cavitands and capsules [J].

Biros, Shannon M. ;

Rebek, Julius, Jr. .

CHEMICAL SOCIETY REVIEWS, 2007, 36 (01) :93-104

[9]

Bong DT, 2001, ANGEW CHEM INT EDIT, V40, P988, DOI 10.1002/1521-3773(20010316)40:6<988::AID-ANIE9880>3.3.CO

[10]

2-E

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