Structure and binding properties of water-soluble cavitands and capsules

被引：356

作者：

Biros, Shannon M. ^{[1
]}

Rebek, Julius, Jr. ^{[1
]}

机构：

[1] Scripps Res Inst, Skaggs Inst Chem Biol, Dept Chem, 10550 N Torrey Pines Rd,MB26, La Jolla, CA 92037 USA

来源：

CHEMICAL SOCIETY REVIEWS | 2007年 / 36卷 / 01期

关键词：

D O I：

10.1039/b508530f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Synthetic receptors are modern tools for investigations into the forces involved in recognition. A widely exploited class of receptors are the resorcin[4]arene-based cavitands and capsules. This critical review (71 references) describes the evolution of water-soluble versions of these structures, along with insights the resulting host-ndash complexes have provided with regard to complexation driving forces in water. An emphasis has been placed on the influence of host structure on guest affinity and dynamics.

引用

页码：93 / 104

页数：12

共 78 条

[1] Water-soluble resorcin[4]arene: Complexation of anionic aromatic guests by cooperativity of electrostatic and hydrophobic interactions
Ahn, DR
Kim, TW
Hong, JI
[J]. TETRAHEDRON LETTERS, 1999, 40 (33) : 6045 - 6048
[2] Baeyer A., 1872, Berichte Der Dtsch. Chem. Ges, V5, P280, DOI [10.1002/cber.18720050186, DOI 10.1002/CBER.18720050186]
[3] Kinetically stable complexes in water: The role of hydration and hydrophobicity
Biros, SM
Ullrich, EC
Hof, F
Trembleau, L
Rebek, J
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (09) : 2870 - 2876
[4] Boerrigter H, 1997, LIEBIGS ANN-RECL, P2247
[5] SYNTHESIS, BINDING-PROPERTIES AND CRYSTAL-STRUCTURE OF A HEMICARCERAND CONTAINING 4 PENTAMETHYLENEDIOXY GROUPS SPANNING 2 BOWLS
BYUN, YS
ROBBINS, TA
KNOBLER, CB
CRAM, DJ
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1995, (19) : 1947 - 1948
[6] Casnati A, 2001, CALIXARENES 2001, P440
[7] Supermolecules by design
Caulder, DL
Raymond, KN
[J]. ACCOUNTS OF CHEMICAL RESEARCH, 1999, 32 (11) : 975 - 982
[8] The rational design of high symmetry coordination clusters
Caulder, DL
Raymond, KN
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1999, (08): : 1185 - 1200
[9] Water-soluble molecular capsules: Self-assembly and binding properties
Corbellini, F
Knegtel, RMA
Grootenhuis, PDJ
Crego-Calama, M
Reinhoudt, DN
[J]. CHEMISTRY-A EUROPEAN JOURNAL, 2005, 11 (01) : 298 - 307
[10] Guest encapsulation in a water-soluble molecular capsule based on ionic interactions
Corbellini, F
Di Costanzo, L
Crego-Calama, M
Geremia, S
Reinhoudt, DN
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (33) : 9946 - 9947

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