Structure and binding properties of water-soluble cavitands and capsules

被引:356
作者
Biros, Shannon M. [1 ]
Rebek, Julius, Jr. [1 ]
机构
[1] Scripps Res Inst, Skaggs Inst Chem Biol, Dept Chem, 10550 N Torrey Pines Rd,MB26, La Jolla, CA 92037 USA
关键词
D O I
10.1039/b508530f
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Synthetic receptors are modern tools for investigations into the forces involved in recognition. A widely exploited class of receptors are the resorcin[4]arene-based cavitands and capsules. This critical review (71 references) describes the evolution of water-soluble versions of these structures, along with insights the resulting host-ndash complexes have provided with regard to complexation driving forces in water. An emphasis has been placed on the influence of host structure on guest affinity and dynamics.
引用
收藏
页码:93 / 104
页数:12
相关论文
共 78 条
  • [1] Water-soluble resorcin[4]arene: Complexation of anionic aromatic guests by cooperativity of electrostatic and hydrophobic interactions
    Ahn, DR
    Kim, TW
    Hong, JI
    [J]. TETRAHEDRON LETTERS, 1999, 40 (33) : 6045 - 6048
  • [2] Baeyer A., 1872, Berichte Der Dtsch. Chem. Ges, V5, P280, DOI [10.1002/cber.18720050186, DOI 10.1002/CBER.18720050186]
  • [3] Kinetically stable complexes in water: The role of hydration and hydrophobicity
    Biros, SM
    Ullrich, EC
    Hof, F
    Trembleau, L
    Rebek, J
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (09) : 2870 - 2876
  • [4] Boerrigter H, 1997, LIEBIGS ANN-RECL, P2247
  • [5] SYNTHESIS, BINDING-PROPERTIES AND CRYSTAL-STRUCTURE OF A HEMICARCERAND CONTAINING 4 PENTAMETHYLENEDIOXY GROUPS SPANNING 2 BOWLS
    BYUN, YS
    ROBBINS, TA
    KNOBLER, CB
    CRAM, DJ
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1995, (19) : 1947 - 1948
  • [6] Casnati A, 2001, CALIXARENES 2001, P440
  • [7] Supermolecules by design
    Caulder, DL
    Raymond, KN
    [J]. ACCOUNTS OF CHEMICAL RESEARCH, 1999, 32 (11) : 975 - 982
  • [8] The rational design of high symmetry coordination clusters
    Caulder, DL
    Raymond, KN
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1999, (08): : 1185 - 1200
  • [9] Water-soluble molecular capsules: Self-assembly and binding properties
    Corbellini, F
    Knegtel, RMA
    Grootenhuis, PDJ
    Crego-Calama, M
    Reinhoudt, DN
    [J]. CHEMISTRY-A EUROPEAN JOURNAL, 2005, 11 (01) : 298 - 307
  • [10] Guest encapsulation in a water-soluble molecular capsule based on ionic interactions
    Corbellini, F
    Di Costanzo, L
    Crego-Calama, M
    Geremia, S
    Reinhoudt, DN
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (33) : 9946 - 9947