The exclusivity of multivalency in dynamic covalent processes

被引：63

作者：

Badjic, JD

Cantrill, SJ

Grubbs, RH ^{[1
]}

Guidry, EN

Orenes, R

Stoddart, JF

机构：

[1] CALTECH, Arnold & Mabel Beckman Lab Chem Synth, Div Chem & Chem Engn, Pasadena, CA 91125 USA

[2] Univ Calif Los Angeles, Calif Nanosyst Inst, Los Angeles, CA 90095 USA

[3] Univ Calif Los Angeles, Dept Chem & Biochem, Los Angeles, CA 90095 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2004年 / 43卷 / 25期

关键词：

metathesis; molecular recognition; NMR spectroscopy; supramolecular chemistry;

D O I：

10.1002/anie.200453963

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Less is more: It is much less efficient to synthesize both components of a multivalent recognition site separately than it is to use one multivalent component to act as a template for the catalytically orchestrated construction of the other component, as demonstrated by the formation of the mechanically interlocked, triply threaded molecular bundle shown. The situation is reiniscent of nature.

引用

页码：3273 / 3278

页数：6

共 65 条

[1] High-avidity, low-affinity multivalent interactions and the block to polyspermy in Xenopus laevis
Arranz-Plaza, E
Tracy, AS
Siriwardena, A
Pierce, JM
Boons, GJ
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (44) : 13035 - 13046
[2] DIALKYLAMMONIUM ION CROWN-ETHER COMPLEXES - THE FORERUNNERS OF A NEW FAMILY OF INTERLOCKED MOLECULES
ASHTON, PR
CAMPBELL, PJ
CHRYSTAL, EJT
GLINK, PT
MENZER, S
PHILP, D
SPENCER, N
STODDART, JF
TASKER, PA
WILLIAMS, DJ
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1995, 34 (17): : 1865 - 1869
[3] Pseudorotaxanes formed between secondary dialkylammonium salts and crown ethers
Ashton, PR
Chrystal, EJT
Glink, PT
Menzer, S
Schiavo, C
Spencer, N
Stoddart, JF
Tasker, PA
White, AJP
Williams, DJ
[J]. CHEMISTRY-A EUROPEAN JOURNAL, 1996, 2 (06) : 709 - 728
[4] ASHTON PR, 1995, ANGEW CHEM, V107, P1997
[5] A mechanically interlocked bundle
Badjic, JD
Balzani, V
Credi, A
Lowe, JN
Silvi, S
Stoddart, JF
[J]. CHEMISTRY-A EUROPEAN JOURNAL, 2004, 10 (08) : 1926 - 1935
[6] Can multivalency be expressed kinetically? The answer is yes
Badjic, JD
Cantrill, SJ
Stoddart, JF
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (08) : 2288 - 2289
[7] BALZAI V, 2003, MOL DEVICES MACHINES
[8] Controlling multivalent interactions in triply-threaded two-component superbundles
Balzani, V
Clemente-León, M
Credi, A
Lowe, JN
Badjic, JD
Stoddart, JF
Williams, DJ
[J]. CHEMISTRY-A EUROPEAN JOURNAL, 2003, 9 (21) : 5348 - 5360
[9] Balzani V, 2000, ANGEW CHEM INT EDIT, V39, P3348, DOI 10.1002/1521-3773(20001002)39:19<3348::AID-ANIE3348>3.0.CO
[10] 2-X

← 1 2 3 4 5 6 7 →