The exclusivity of multivalency in dynamic covalent processes

被引：63

作者：

Badjic, JD

Cantrill, SJ

Grubbs, RH ^{[1
]}

Guidry, EN

Orenes, R

Stoddart, JF

机构：

[1] CALTECH, Arnold & Mabel Beckman Lab Chem Synth, Div Chem & Chem Engn, Pasadena, CA 91125 USA

[2] Univ Calif Los Angeles, Calif Nanosyst Inst, Los Angeles, CA 90095 USA

[3] Univ Calif Los Angeles, Dept Chem & Biochem, Los Angeles, CA 90095 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2004年 / 43卷 / 25期

关键词：

metathesis; molecular recognition; NMR spectroscopy; supramolecular chemistry;

D O I：

10.1002/anie.200453963

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Less is more: It is much less efficient to synthesize both components of a multivalent recognition site separately than it is to use one multivalent component to act as a template for the catalytically orchestrated construction of the other component, as demonstrated by the formation of the mechanically interlocked, triply threaded molecular bundle shown. The situation is reiniscent of nature.

引用

页码：3273 / 3278

页数：6

共 65 条

[61] New molecular topologies by fourfold metathesis reactions within a hydrogen-bonded calix[4]arene dimer
Vysotsky, MO
Bolte, M
Thondorf, I
Böhmer, V
[J]. CHEMISTRY-A EUROPEAN JOURNAL, 2003, 9 (14) : 3375 - 3382
[62] Synthesis of catenane structures via ring-closing metathesis
Weck, M
Mohr, B
Sauvage, JP
Grubbs, RH
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1999, 64 (15) : 5463 - 5471
[63] Structural basis of lectin-carbohydrate recognition
Weis, WI
Drickamer, K
[J]. ANNUAL REVIEW OF BIOCHEMISTRY, 1996, 65 : 441 - 473
[64] Anion-templated rotaxane formation
Wisner, JA
Beer, PD
Drew, MGB
Sambrook, MR
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (42) : 12469 - 12476
[65] Altering the strength of lectin binding interactions and controlling the amount of lectin clustering using mannose/hydroxyl-functionalized dendrimers
Woller, EK
Walter, ED
Morgan, JR
Singel, DJ
Cloninger, MJ
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (29) : 8820 - 8826

← 1 2 3 4 5 6 7 →