Organic-inorganic hybrid sol-gel materials incorporating functionalized cobalt(III) corroles for the selective detection of CO

被引：63

作者：

Barbe, JM ^{[1
]}

Canard, G ^{[1
]}

Brandès, S ^{[1
]}

Guilard, R ^{[1
]}

机构：

[1] Univ Bourgogne, Fac Sci Gabriel, LIMSAG, UMR 5633, F-21100 Dijon, France

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2005年 / 44卷 / 20期

关键词：

carbon monoxide sensors; cobalt; organic-inorganic hybrid composites; porphyrinoids; sol-gel processes;

D O I：

10.1002/anie.200463009

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) Selective adsorption of CO over N2 and O2 by the title compounds make these materials ideal candidates for use in CO sensors (see picture). The materials are prepared by a sol-gel process and exhibit greater chemical stability than analogous isolated cobalt(III) corrole complexes. © 2005 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：3103 / 3106

页数：4

共 41 条

[1]

Adima A, 2000, CHIRALITY, V12, P411, DOI 10.1002/(SICI)1520-636X(2000)12:5/6<411::AID-CHIR21>3.3.CO

[2]

2-O

[3] Metallocorroles as sensing components for gas sensors:: remarkable affinity and selectivity of cobalt(III) corroles for CO vs. O2 and N2 [J].

Barbe, JM ;

Canard, G ;

Brandès, S ;

Jérôme, F ;

Dubois, G ;

Guilard, R .

DALTON TRANSACTIONS, 2004, (08) :1208-1214

[4] THE DETERMINATION OF PORE VOLUME AND AREA DISTRIBUTIONS IN POROUS SUBSTANCES .1. COMPUTATIONS FROM NITROGEN ISOTHERMS [J].

BARRETT, EP ;

JOYNER, LG ;

HALENDA, PP .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1951, 73 (01) :373-380

[5] Exploring the properties and optical sensing capability of sol-gel materials containing a covalently bonded binucleating cryptand [J].

Basallote, MG ;

Blanco, E ;

Blázquez, M ;

Fernández-Trujillo, MJ ;

Litrán, R ;

Máñez, MA ;

del Solar, MR .

CHEMISTRY OF MATERIALS, 2003, 15 (10) :2025-2032

[6] Sol gel-immobilised terbium complexes for luminescent sensing of dissolved oxygen by analysis of emission decay [J].

Blair, S ;

Kataky, R ;

Parker, D .

NEW JOURNAL OF CHEMISTRY, 2002, 26 (05) :530-535

[7] Tailoring of organically modified silicas for the solid-liquid extraction of actinides [J].

Bourg, S ;

Broudic, JC ;

Conocar, O ;

Moreau, JJE ;

Meyer, D ;

Man, MWC .

CHEMISTRY OF MATERIALS, 2001, 13 (02) :491-499

[8] Auto-organization in sol-gel type polycondensation: A door to the nanosciences [J].

Boury, B ;

Corriu, R .

CHEMICAL RECORD, 2003, 3 (02) :120-132

[9] Auto-organisation of hybrid organic-inorganic materials prepared by sol-gel process [J].

Boury, B ;

Corriu, RJP .

CHEMICAL COMMUNICATIONS, 2002, (08) :795-802

[10] Adsorption of gases in multimolecular layers [J].

Brunauer, S ;

Emmett, PH ;

Teller, E .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1938, 60 :309-319

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