A 3D chiral Zn(II) coordination polymer with triple Zn-oba-Zn helical chains (oba=4,4′-oxybis(benzoate))

被引：139

作者：

Ma, Yi

Han, Zhengbo ^{[1
]}

He, Yongke

Yang, Liguo

机构：

[1] Liaoning Univ, Coll Chem, Shenyang 110036, Peoples R China

[2] Jilin Univ, Alan G MacDiarmid Inst, Changchun 130012, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2007年 / 40期

关键词：

D O I：

10.1039/b708479j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The solvothermal reaction of Zn( II) and 4,4'- oxybis( benzoic acid) in the presence of anhydrous ethanol leads to the generation of a novel 3D chiral coordination polymer with triple helical chains; the resulting crystals were not a racemic mixture but had an enantiomeric excess, which was confirmed by measuring the optical rotation of bulk samples using solid state vibrational circular dichroism ( VCD).

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页码：4107 / 4109

页数：3

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