Chiral packing of chiral quintuple layers polycatenated to give a three-dimensional network in the coordination polymer [Co5(bpe)9(H2O)8(SO4)4](SO4)•14H2O [bpe=1,2-bis(4-pyridyl)ethane]

被引：165

作者：

Carlucci, L

Ciani, G

Proserpio, DM

Rizzato, S

机构：

[1] Dipartimento Chim Strutturale & Steriochim Inorga, I-20133 Milan, Italy

[2] Univ Milan, Ctr CNR, I-20133 Milan, Italy

[3] Univ Insubria, Dipartimento Biol Strutturale & Funz, I-21100 Varese, Italy

来源：

CHEMICAL COMMUNICATIONS | 2000年 / 14期

关键词：

D O I：

10.1039/b002021o

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of cobalt(II) sulfate with 1,2-bis(4-pyridyl)ethane gives a crystalline polymeric species comprised of chiral quintuple layers with five decks of linear chains rotated by 120 degrees from level to level, that are perpendicularly joined via five-metal helical motifs; furthermore, each of these two-dimensional frames is catenated by the neighbouring layers to give an overall three-dimensional chiral nanoporous architecture.

引用

页码：1319 / 1320

页数：2

共 28 条

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