Effects of sewage sludge blending on the coal combustion:: A thermogravimetric assessment

被引:109
作者
Otero, M.
Gomez, X.
Garcia, A. I.
Moran, A.
机构
[1] Univ Leon, Nat Resources Inst, Dept Chem Engn, E-24071 Leon, Spain
[2] Univ Aveiro, Ctr Environm & Marine Studies, Dept Chem, P-3810193 Aveiro, Portugal
关键词
co-combustion; sewage sludge; coal; thermogravimetric analysis; kinetics;
D O I
10.1016/j.chemosphere.2007.05.077
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
Combustion of urban sewage sludge together with coal in existing infrastructures may be a sustainable management option energetically interesting, for these materials, usually considered wastes. Thermogravimetric analysis was used to study the combustion of a semi-anthracite coal and the modifications undergone when adding a small percentage (2%, 5%, 10%) of sewage sludge. Both Differential Scanning, Calorimetric analysis and Differential Thermogravimetry burning profiles showed differences between coal and sewage sludge combustion. However. the effects of adding a percentage of sewage sludge equal or smaller than 10% was hardly noticeable in terms of heat release and weight loss during the coal combustion. This was further proved by non-isothermal kinetic analysis, which was used to evaluate the Arrhenius activation energy corresponding to the co-combustion of the blends. This work shows that thermogravimetric analysis may be used as an easy rapid tool to asses the co-combustion of sewage sludge together with coal. (C) 2007 Elsevier Ltd. All rights reserved.
引用
收藏
页码:1740 / 1750
页数:11
相关论文
共 56 条
[1]  
*ASTM, E872 ASTM
[2]  
*ASTM, D1102 ASTM
[3]  
*ASTM, 3173 ASTM D
[4]  
*ASTM, 3174 ASTM D
[5]  
*ASTM, 3175 ASTM D
[6]  
*ASTM, 3171 ASTM D
[7]  
*ASTM, E870 ASTM
[8]   TG-MS as a technique for a better monitoring of the pyrolysis, gasification and combustion of two kinds of sewage sludge [J].
Calvo, LF ;
Sánchez, ME ;
Morán, A ;
García, AI .
JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2004, 78 (02) :587-598
[9]   Heating process characteristics and kinetics of sewage sludge in different atmospheres [J].
Calvo, LF ;
Otero, M ;
Jenkins, BM ;
García, AI ;
Morán, A .
THERMOCHIMICA ACTA, 2004, 409 (02) :127-135
[10]   Biosolids - A fuel or a waste? An integrated appraisal of five co-cornhustion scenarios with policy analysis [J].
Cartmell, E ;
Gostelow, P ;
Riddell-Black, D ;
Simms, N ;
Oakey, J ;
Morris, J ;
Jeffrey, P ;
Howsam, P ;
Pollard, SJ .
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2006, 40 (03) :649-658