Aluminosilicate catalysis of chalcone diels-alder reactions

被引：9

作者：

Corbett, Jennifer L. ^{[1
]}

Weavers, Rex T. ^{[1
]}

机构：

[1] Univ Otago, Dept Chem, Dunedin 9054, New Zealand

来源：

SYNTHETIC COMMUNICATIONS | 2008年 / 38卷 / 04期

关键词：

aluminosilicate catalyst; chalcone; Diels-Alder; isoprene; myrcene;

D O I：

10.1080/00397910701796527

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Previously unreported Diels-Alder adducts of substituted chalcones with isoprene and myrcene have been formed at more than 0 degrees C by employing a nanoporous aluminosilicate catalyst. This catalyst eliminates problems with diene polymerization that are encountered with many other Lewis acids. The chalcone component has some size restrictions.

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页码：489 / 498

页数：10

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