Perovskite Solar Cells: Beyond Methylammonium Lead Iodide

被引:270
作者
Boix, Pablo P. [1 ]
Agarwala, Shweta [1 ]
Koh, Teck Ming [1 ]
Mathews, Nripan [1 ,2 ]
Mhaisalkar, Subodh G. [1 ,2 ]
机构
[1] Nanyang Technol Univ ERI N, Energy Res Inst, Singapore 637553, Singapore
[2] Nanyang Technol Univ, Sch Mat Sci & Engn, Singapore 639798, Singapore
来源
JOURNAL OF PHYSICAL CHEMISTRY LETTERS | 2015年 / 6卷 / 05期
关键词
OPEN-CIRCUIT VOLTAGE; ORGANIC-INORGANIC PEROVSKITES; REDUCED BAND-GAP; HALIDE PEROVSKITES; OPTICAL-PROPERTIES; SEQUENTIAL DEPOSITION; ABSORPTION-SPECTRUM; HYBRID PEROVSKITE; PHASE-TRANSITIONS; TIN;
D O I
10.1021/jz502547f
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Organic-inorganic lead halide based perovskites solar cells are by far the highest efficiency solution-processed solar cells, threatening to challenge thin film and polycrystalline silicon ones. Despite the intense research in this area, concerns surrounding the long-term stability as well as the toxicity of lead in the archetypal perovskite, CH3NH3PbI3, have the potential to derail commercialization. Although the search for Pb-free perovskites have naturally shifted to other transition metal cations and formulations that replace the organic moiety, efficiencies with these substitutions are still substantially lower than those of the Pb-perovskite. The perovskite family offers rich multitudes of crystal structures and substituents with the potential to uncover new and exciting photophysical phenomena that hold the promise of higher solar cell efficiencies. In addressing materials beyond CH3NH3PbI3, this Perspective will discuss a broad palette of elemental substitutions, solid solutions, and multidimensional families that will provide the next fillip toward market viability of the perovskite solar cells.
引用
收藏
页码:898 / 907
页数:10
相关论文
共 84 条
[1]  
[Anonymous], 1999, PROG INORG CHEM
[2]  
[Anonymous], ANGEW CHEM
[3]  
[Anonymous], NANOSCALE
[4]   Synthesis and crystal chemistry of the hybrid perovskite (CH3NH3) PbI3 for solid-state sensitised solar cell applications [J].
Baikie, Tom ;
Fang, Yanan ;
Kadro, Jeannette M. ;
Schreyer, Martin ;
Wei, Fengxia ;
Mhaisalkar, Subodh G. ;
Graetzel, Michael ;
White, Tim J. .
JOURNAL OF MATERIALS CHEMISTRY A, 2013, 1 (18) :5628-5641
[5]   Low-temperature processed meso-superstructured to thin-film perovskite solar cells [J].
Ball, James M. ;
Lee, Michael M. ;
Hey, Andrew ;
Snaith, Henry J. .
ENERGY & ENVIRONMENTAL SCIENCE, 2013, 6 (06) :1739-1743
[6]   Sequential deposition as a route to high-performance perovskite-sensitized solar cells [J].
Burschka, Julian ;
Pellet, Norman ;
Moon, Soo-Jin ;
Humphry-Baker, Robin ;
Gao, Peng ;
Nazeeruddin, Mohammad K. ;
Graetzel, Michael .
NATURE, 2013, 499 (7458) :316-+
[7]   High performance hybrid solar cells sensitized by organolead halide perovskites [J].
Cai, Bing ;
Xing, Yedi ;
Yang, Zhou ;
Zhang, Wen-Hua ;
Qiu, Jieshan .
ENERGY & ENVIRONMENTAL SCIENCE, 2013, 6 (05) :1480-1485
[8]   Structural diversity and chemical trends in hybrid inorganic-organic framework materials [J].
Cheetham, Anthony K. ;
Rao, C. N. R. ;
Feller, Russell K. .
CHEMICAL COMMUNICATIONS, 2006, (46) :4780-4795
[9]   Layered organic-inorganic hybrid perovskites: structure, optical properties, film preparation, patterning and templating engineering [J].
Cheng, Ziyong ;
Lin, Jun .
CRYSTENGCOMM, 2010, 12 (10) :2646-2662
[10]   All-solid-state dye-sensitized solar cells with high efficiency [J].
Chung, In ;
Lee, Byunghong ;
He, Jiaqing ;
Chang, Robert P. H. ;
Kanatzidis, Mercouri G. .
NATURE, 2012, 485 (7399) :486-U94