Functional resins as innovative supports for catalytically active metal nanoclusters

被引:39
作者
Corain, B
Centomo, P
Lora, S
Kralik, M
机构
[1] CNR, Ist Sci & Tecnol Mol, Dipartimento Chim Inorgan Metallorgan Analit, Sez Padova, I-35131 Padua, Italy
[2] CNR, Ist Sintesi Organ & Fotoreatt, I-35020 Legnaro, Italy
[3] Slovak Univ Technol Bratislava, Dept Organ Technol, Bratislava 81237 1, Slovakia
关键词
metal catalysis; functional resins; palladium; metal nanoclusters; innovative supports;
D O I
10.1016/S1381-1169(03)00361-3
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Functional resins are plausible candidates for supporting catalytically active metal nanoclusters alternative, or complementary to conventional supports such as amorphous carbon, metal oxides, zeolites. Mechanical and thermal stabilities are fair and perfectly suitable to application in the realm of fine chemistry. The polymer framework turns out to be a designable template for controlling nanoclusters size and size distributions. (C) 2003 Elsevier Science B.V All rights reserved.
引用
收藏
页码:755 / 762
页数:8
相关论文
共 35 条
[11]   Catalysis and polymer networks -: the role of morphology and molecular accessibility [J].
Corain, B ;
Zecca, M ;
Jerábek, K .
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2001, 177 (01) :3-20
[12]  
CORAIN B, 2001, J MOL CATAL A-CHEM, V173, P61
[13]   The issue of morphology and molecular accessibility of swollen gel-type resins: An integrated inverse steric exclusion chromatography electron spin resonance NMR approach [J].
D'Archivio, AA ;
Galantini, L ;
Panatta, A ;
Tettamanti, E ;
Corain, B .
JOURNAL OF PHYSICAL CHEMISTRY B, 1998, 102 (35) :6774-6779
[14]   Metal palladium dispersed inside macroporous ion-exchange resins: rotational and translational mobility inside the polymer network [J].
D'Archivio, AA ;
Galantini, L ;
Tettamanti, E ;
Panatta, A ;
Corain, B .
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2000, 157 (1-2) :269-273
[15]  
GUYOT A, 1998, SYNTHESIS SEPARATION, P1
[16]   Advances in the catalysis of Au nanoparticles [J].
Haruta, M ;
Daté, M .
APPLIED CATALYSIS A-GENERAL, 2001, 222 (1-2) :427-437
[17]   Promotion in heterogeneous catalysis: a topic requiring a new approach? [J].
Hutchings, GJ .
CATALYSIS LETTERS, 2001, 75 (1-2) :1-12
[18]  
Jerabek K, 1996, ACS SYM SER, V635, P211
[19]   CHARACTERIZATION OF SWOLLEN POLYMER GELS USING SIZE EXCLUSION CHROMATOGRAPHY [J].
JERABEK, K .
ANALYTICAL CHEMISTRY, 1985, 57 (08) :1598-1602
[20]   Polymer frameworks as templates for generating size-controlled metal nanoclusters. Active and reusable metal catalysts based on organic resins and on organic/inorganic composites [J].
Kralik, M ;
Kratky, V ;
Centomo, P ;
Guerriero, P ;
Lora, S ;
Corain, B .
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2003, 195 (1-2) :219-223