One saccharide sensor based on the complex of the boronic acid and the monosaccharide using electrochemical impedance spectroscopy

被引:52
作者
Ma, Y [1 ]
Yang, XR [1 ]
机构
[1] Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Electroanalyt Chem, Changchun 130022, Jilin, Peoples R China
基金
中国国家自然科学基金;
关键词
poly (aminophenyl boronic acid); saccharide; electrochemical impedance spectroscopy;
D O I
10.1016/j.jelechem.2005.03.027
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
A novel saccharide sensor based on the covalent interaction between the boronic acid and saccharides was developed. Poly (aminophenylboronic acid) (PABA) was prepared by electropolymerizing 3-aminophenylboronic acid on gold electrode surface in acidic solution. The boronic acid group of the PABA film can form covalent-bond with different saccharides, which can change the dielectric characteristics of the PABA film, and the change of the dielectric characteristic was saccharides concentration dependent. Four kinds of saccharides could be detected by using electrochemical impedance spectroscopy. Good linear relationship and high sensitivity were obtained by this method. (c) 2005 Elsevier B.V. All rights reserved.
引用
收藏
页码:348 / 352
页数:5
相关论文
共 33 条
[1]  
[Anonymous], 1980, FUNDAMENTALS APPL
[2]   Sensing and amplification of oligonucleotide-DNA interactions by means of impedance spectroscopy: a route to a Tay-Sachs sensor [J].
Bardea, A ;
Patolsky, F ;
Dagan, A ;
Willner, I .
CHEMICAL COMMUNICATIONS, 1999, (01) :21-22
[3]   BIOCATALYSIS BY SOL-GEL ENTRAPPED ENZYMES [J].
BRAUN, S ;
SHTELZER, S ;
RAPPOPORT, S ;
AVNIR, D ;
OTTOLENGHI, M .
JOURNAL OF NON-CRYSTALLINE SOLIDS, 1992, 147 :739-743
[4]   Faradaic impedance behaviour of oxidized and reduced poly (2,5-di-(-2-thienyl)-thiophene) films [J].
Brillas, E ;
Cabot, PL ;
Garrido, JA ;
Montilla, M ;
Rodriguez, RM ;
Carrasco, J .
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1997, 430 (1-2) :133-140
[5]   Improvement of the output characteristics of amperometric enzyme electrode by using the powder microelectrode technique [J].
Cha, CS ;
Chen, J ;
Liu, PF .
BIOSENSORS & BIOELECTRONICS, 1998, 13 (01) :87-94
[6]   Capacitive detection of glucose using molecularly imprinted polymers [J].
Cheng, ZL ;
Wang, EK ;
Yang, XR .
BIOSENSORS & BIOELECTRONICS, 2001, 16 (03) :179-185
[7]   Poly(aniline boronic acid)-based conductimetric sensor of dopamine [J].
Fabre, B ;
Taillebois, L .
CHEMICAL COMMUNICATIONS, 2003, (24) :2982-2983
[8]   Characterization of the swelling of acrylamidophenylboronic acid-acrylamide hydrogels upon interaction with glucose by faradaic impedance spectroscopy, chronopotentiometry, quartz-crystal microbalance (QCM), and surface plasmon resonance (SPR) experiments [J].
Gabai, R ;
Sallacan, N ;
Chegel, V ;
Bourenko, T ;
Katz, E ;
Willner, I .
JOURNAL OF PHYSICAL CHEMISTRY B, 2001, 105 (34) :8196-8202
[9]   Fluorescent saccharide receptors: A sweet solution to the design, assembly and evaluation of boronic acid derived PET sensors [J].
James, TD ;
Linnane, P ;
Shinkai, S .
CHEMICAL COMMUNICATIONS, 1996, (03) :281-288
[10]   Impedance spectroscopy of self-assembled monolayers on Au(111): Evidence for complex double-layer structure in aqueous NaClO4 at the potential of zero charge [J].
Janek, RP ;
Fawcett, WR ;
Ulman, A .
JOURNAL OF PHYSICAL CHEMISTRY B, 1997, 101 (42) :8550-8558