共 33 条
One saccharide sensor based on the complex of the boronic acid and the monosaccharide using electrochemical impedance spectroscopy
被引:52
作者:
Ma, Y
[1
]
Yang, XR
[1
]
机构:
[1] Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Electroanalyt Chem, Changchun 130022, Jilin, Peoples R China
基金:
中国国家自然科学基金;
关键词:
poly (aminophenyl boronic acid);
saccharide;
electrochemical impedance spectroscopy;
D O I:
10.1016/j.jelechem.2005.03.027
中图分类号:
O65 [分析化学];
学科分类号:
070302 ;
081704 ;
摘要:
A novel saccharide sensor based on the covalent interaction between the boronic acid and saccharides was developed. Poly (aminophenylboronic acid) (PABA) was prepared by electropolymerizing 3-aminophenylboronic acid on gold electrode surface in acidic solution. The boronic acid group of the PABA film can form covalent-bond with different saccharides, which can change the dielectric characteristics of the PABA film, and the change of the dielectric characteristic was saccharides concentration dependent. Four kinds of saccharides could be detected by using electrochemical impedance spectroscopy. Good linear relationship and high sensitivity were obtained by this method. (c) 2005 Elsevier B.V. All rights reserved.
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页码:348 / 352
页数:5
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