Dimethylsulfide oxidation and the ratio of methanesulfonate to non sea-salt sulfate in the marine aerosol

被引：48

作者：

Ayers, GP

Cainey, JM

Granek, H

Leck, C

机构：

[1] UNIV STOCKHOLM,DEPT METEOROL,S-10691 STOCKHOLM,SWEDEN

[2] MONASH UNIV,GIPPSLAND CTR ENVIRONM SCI,CHURCHILL,AUSTRALIA

来源：

JOURNAL OF ATMOSPHERIC CHEMISTRY | 1996年 / 25卷 / 03期

关键词：

DMS oxidation; marine aerosol; box model; cloud condensation nuclei; non sea-salt sulfate;

D O I：

10.1007/BF00053798

中图分类号：

X [环境科学、安全科学];

学科分类号：

08 ; 0830 ;

摘要：

A box model of DMS oxidation in the clean, low-NO, marine atmospheric boundary layer has been used to predict the latitude dependence of the aerosol methanesulfonate to non sea-salt sulfate ratio. The observed latitude dependence of this ratio in the Southern Hemisphere can be reproduced reasonably well if the full suite of reactions proposed by Yin ct al. (1990a) is employed, and a strong temperature dependence is specified in the rates of decomposition of CH3SO2 and CH3SO3 radicals.

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收藏

页码：307 / 325

页数：19

相关论文

共 55 条

[1] AEROSOLS, CLOUD MICROPHYSICS, AND FRACTIONAL CLOUDINESS [J].

ALBRECHT, BA .

SCIENCE, 1989, 245 (4923) :1227-1230

[2] BIOGENIC SULFUR EMISSIONS AND AEROSOLS OVER THE TROPICAL SOUTH-ATLANTIC .3. ATMOSPHERIC DIMETHYLSULFIDE, AEROSOLS AND CLOUD CONDENSATION NUCLEI [J].

ANDREAE, MO ;

ELBERT, W ;

DEMORA, SJ .

JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES, 1995, 100 (D6) :11335-11356

[3] EVIDENCE FOR PHOTOCHEMICAL CONTROL OF OZONE CONCENTRATIONS IN UNPOLLUTED MARINE AIR [J].

AYERS, GP ;

PENKETT, SA ;

GILLETT, RW ;

BANDY, B ;

GALBALLY, IE ;

MEYER, CP ;

ELSWORTH, CM ;

BENTLEY, ST ;

FORGAN, BW .

NATURE, 1992, 360 (6403) :446-449

[4] The annual cycle of peroxides and ozone in marine air at Cape Grim, Tasmania [J].

Ayers, GP ;

Penkett, SA ;

Gillett, RW ;

Bandy, B ;

Galbally, IE ;

Meyer, CP ;

Elsworth, CM ;

Bentley, ST ;

Forgan, BW .

JOURNAL OF ATMOSPHERIC CHEMISTRY, 1996, 23 (03) :221-252

[5] COHERENCE BETWEEN SEASONAL CYCLES OF DIMETHYL SULFIDE, METHANESULFONATE AND SULFATE IN MARINE AIR [J].

AYERS, GP ;

IVEY, JP ;

GILLETT, RW .

NATURE, 1991, 349 (6308) :404-406

[6]

AYERS GP, 1995, BASELINE 92 BASELINE

[7] LOW YIELDS OF SO2 FROM DIMETHYL SULFIDE OXIDATION IN THE MARINE BOUNDARY-LAYER [J].

BANDY, AR ;

SCOTT, DL ;

BLOMQUIST, BW ;

CHEN, SM ;

THORNTON, DC .

GEOPHYSICAL RESEARCH LETTERS, 1992, 19 (11) :1125-1127

[8] Role of adducts in the atmospheric oxidation of dimethyl sulfide [J].

Barone, SB ;

Turnipseed, AA ;

Ravishankara, AR .

FARADAY DISCUSSIONS, 1995, 100 :39-54

[9] REGIONAL AND SEASONAL-VARIATIONS IN THE FLUX OF OCEANIC CARBON-MONOXIDE TO THE ATMOSPHERE [J].

BATES, TS ;

KELLY, KC ;

JOHNSON, JE ;

GAMMON, RH .

JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES, 1995, 100 (D11) :23093-23101

[10] VARIATIONS IN THE METHANESULFONATE TO SULFATE MOLAR RATIO IN SUBMICROMETER MARINE AEROSOL-PARTICLES OVER THE SOUTH-PACIFIC OCEAN [J].

BATES, TS ;

CALHOUN, JA ;

QUINN, PK .

JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES, 1992, 97 (D9) :9859-9865

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