Transient elongational viscosity of LLDPE/LDPE blends and its relevance to bubble stability in the film blowing process

被引:51
作者
Micic, P [1 ]
Bhattacharya, SN
Field, G
机构
[1] Orica Australia Pty Ltd, Ascot Vale, Vic, Australia
[2] Royal Melbourne Inst Technol, Rheol & Mat Proc Ctr, Melbourne, Vic 3001, Australia
[3] Royal Melbourne Inst Technol, CRC Polymers, Melbourne, Vic 3001, Australia
关键词
D O I
10.1002/pen.10339
中图分类号
TQ [化学工业];
学科分类号
0817 [化学工程与技术];
摘要
Transient elongational viscosity of Linear low density polyethylene (LLDPE) and its blends with 10% and 20% of low density polyethylene (LDPE) was measured at two temperatures by a constant strain rate elongational rheometer. In addition, the performance of the blends in the film blowing process was assessed in terms of bubble stability at two processing temperatures. An operating window for stable bubble production was determined. The elongational viscosity measurements on blends revealed stronger strain hardening characteristics at a higher temperature of testing. These results correlate favorably with findings from a bubble stability investigation where it was found that the size of the operating window for stable bubble production increased with increasing extrusion temperature. This work seems to indicate that increasing processing temperature during the film blowing of LLDPE-rich blends could lead to a processability improvement of these blends as far as bubble stability is concerned.
引用
收藏
页码:1685 / 1693
页数:9
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