New chiral phosphine-amide ligands in palladium-catalysed asymmetric allylic alkylations

被引：33

作者：

Mino, T ^{[1
]}

Kashihara, K

Yamashita, M

机构：

[1] Chiba Univ, Fac Engn, Dept Mat Technol, Inage Ku, Chiba 2638522, Japan

[2] Doshisha Univ, Fac Engn, Dept Mol Sci & Technol, Kyoto 6100394, Japan

来源：

TETRAHEDRON-ASYMMETRY | 2001年 / 12卷 / 02期

关键词：

D O I：

10.1016/S0957-4166(01)00037-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Palladium-catalysed asymmetric allylic alkylation of' 1,3-diphenyl-2-propenyl acetate 8a with a dimethyl malonate-BSA-LiOAc system has been successfully carried out in the presence of new chiral phosphine amide, such as 5, in good yields and high enantiomeric excesses of up to 85%. (C) 2001 Elsevier Science Ltd. All rights reserved.

引用

页码：287 / 291

页数：5

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