Magnetic properties of the UCoAl1-xGax intermetallic system

被引:15
作者
Andreev, AV
Homma, Y
Shiokawa, Y
Sechovsky, V
机构
[1] Charles Univ, Dept Met Phys, CR-12116 Prague 2, Czech Republic
[2] Tohoku Univ, Mat Res Inst, Sendai, Miyagi 98077, Japan
[3] Acad Sci Czech Republ, Inst Phys, CZ-18040 Prague 8, Czech Republic
关键词
uranium intermetallics; metamagnetism; ferromagnetism;
D O I
10.1016/S0925-8388(98)00143-1
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Results of structure and magnetization study of solid solutions UCoAl1-xGax are presented. The ZrNiAl-type structure of parent compounds persists over whole series and a rather weak concentration dependence of lattice parameters is observed. UCoAl is a paramagnet showing metamagnetism above 1 T at low temperatures. Substitution of Ga for Al leads to gradual evolution of spontaneous magnetic moment, which amounts to 0.63 mu(B) in UCoGa. This behaviour associated with the 5f moment formation and ordering is discussed in terms of varying U-U exchange interactions mediated by the anisotropic 5f ligand hybridization. (C) 1998 Elsevier Science S.A.
引用
收藏
页码:34 / 38
页数:5
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