A rapid monotonically convergent iteration algorithm for quantum optimal control over the expectation value of a positive definite operator

被引：262

作者：

Zhu, WS ^{[1
]}

Rabitz, H ^{[1
]}

机构：

[1] Princeton Univ, Dept Chem, Princeton, NJ 08544 USA

来源：

JOURNAL OF CHEMICAL PHYSICS | 1998年 / 109卷 / 02期

关键词：

D O I：

10.1063/1.476575

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A new iteration method is presented for achieving quantum optimal control over the expectation value of a positive definite operator. Theoretical analysis shows that this new algorithm exhibits quadratic and monotonic convergence. Numerical calculations verify that for this new algorithm, within a few steps, the optimized objective functional comes close to its converged limit. (C) 1998 American Institute of Physics.

引用

页码：385 / 391

页数：7

共 10 条

[1] ISOMERIZATIONS CONTROLLED BY ULTRASHORT INFRARED-LASER PULSES - MODEL SIMULATIONS FOR THE INVERSION OF LIGANDS(H) IN THE DOUBLE-WELL POTENTIAL OF AN ORGANOMETALLIC COMPOUND, [(C5H5)(CO)2FEPH2] [J].