Intermolecular dynamics, interactions, and solvation in ionic liquids

被引：245

作者：

Castner, Edward W., Jr. ^{[1
]}

Wishart, James F.

Shirota, Hideaki

机构：

[1] Rutgers State Univ, Dept Chem & Biol Chem, Piscataway, NJ 08854 USA

[2] Brookhaven Natl Lab, Dept Chem, Upton, NY 11973 USA

[3] Chiba Univ, Div Nanosci, Grad Sch Adv Integrat Sci, Inage Ku, Chiba 2638522, Japan

来源：

ACCOUNTS OF CHEMICAL RESEARCH | 2007年 / 40卷 / 11期

关键词：

D O I：

10.1021/ar700169g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Ionic liquids can simultaneously assume multiple solvent roles, because they are strongly polar and polarizable solvents and binary solutions and frequently contain very hydrophobic components. When the cation and anion functional groups are tuned appropriately, ionic liquids can be used as designer solvents for a broad range of applications. In this Account, we discuss our spectroscopic studies on the intermolecular interactions, dynamics, solvation, transport, and friction in ionic liquids, as compared with information obtained from macroscopic experiments including viscometry and calorimetry.

引用

页码：1217 / 1227

页数：11

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