New route to herbertanes via a Suzuki cross-coupling reaction:: synthesis of herbertenediol

被引：18

作者：

Abad, A ^{[1
]}

Agulló, C ^{[1
]}

Cuñat, AC ^{[1
]}

Jiménez, D ^{[1
]}

Perni, RH ^{[1
]}

机构：

[1] Univ Valencia, Fac Quim, Dept Quim Organ, E-46100 Burjassot, Valencia, Spain

来源：

TETRAHEDRON | 2001年 / 57卷 / 48期

关键词：

terpenes; Suzuki reactions; rearrangements; cyclopropanes;

D O I：

10.1016/S0040-4020(01)00987-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The synthesis of herbertenediol, a relevant member of the herbertane-type sesquiterpene family, is described. The synthesis is based on a new general approach to this group of sesquiterpenes where the herbertane skeleton is constructed using a Suzuki cross-coupling reaction and a [2,3]-sigmatropic Still-Wittig rearrangement as key synthetic steps. (C) 2001 Elsevier Science Ltd. All rights reserved.

引用

页码：9727 / 9735

页数：9

共 61 条

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