Borrowing hydrogen in the activation of alcohols

被引：1013

作者：

Hamid, Malai Haniti S. A. ^{[1
]}

Slatford, Paul A. ^{[1
]}

Williams, Jonathan M. J. ^{[1
]}

机构：

[1] Univ Bath, Dept Chem, Bath BA2 7AY, Avon, England

来源：

ADVANCED SYNTHESIS & CATALYSIS | 2007年 / 349卷 / 10期

基金：

英国工程与自然科学研究理事会;

关键词：

alcohols; amines; catalysis; transfer hydrogenation; transition metals;

D O I：

10.1002/adsc.200600638

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Alcohols can be temporarily converted into carbonyl compounds by the metal-catalysed removal of hydrogen. The carbonyl compounds are reactive in a wider range of transformations than the precursor alcohols and can react in situ to give imines, alkenes, and alpha-functionalised carbonyl compounds. The metal catalyst, which had borrowed the hydrogen, then returns it to the transformed carbonyl compound, leading to an overall process in which alcohols can be converted into amines, compounds containing C-C bonds and beta-functionalised alcohols.

引用

页码：1555 / 1575

页数：21

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