Highly efficient molybdenum(II)-catalyzed intramolecular allylic alkylation of arenes

被引：14

作者：

Bandini, Marco ^{[1
]}

Eichholzer, Astrid ^{[1
]}

Kotrusz, Peter ^{[1
]}

Umani-Ronchi, Achille ^{[1
]}

机构：

[1] Univ Bologna, Dipartimento Chim G Ciamician, I-40126 Bologna, Italy

来源：

ADVANCED SYNTHESIS & CATALYSIS | 2008年 / 350卷 / 04期

关键词：

allylic alkylation; catalysis; cyclization; Friedel-Crafts reaction;

D O I：

10.1002/adsc.200700607

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

The Friedel-Crafts-type intramolecular allylic alkylation of simple arenes is performed in the presence of a catalytic amount of [Mo(II) (CO)(4)Br-2](2) (2.5 mol%). The moisture-tolerant protocol provided a mild and direct access to a large library of functionalized 4-vinyl-1,2,3,4-tetrahydronaphthalenes in high yields.

引用

页码：531 / 536

页数：6