Superparamagnetic composite colloids with anisotropic structures

被引:218
作者
Ge, Jianping [1 ]
Hu, Yongxing [1 ]
Zhang, Tierui [1 ]
Yin, Yadong [1 ]
机构
[1] Univ Calif Riverside, Dept Chem, Riverside, CA 92521 USA
关键词
D O I
10.1021/ja0736461
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
We report a unified set of emulsion polymerization processes for the synthesis of a series of spherical and nonspherical magnetite-polystyrene (Fe3O4-PS) composite colloids with the superparamagnetic cores concentrically or eccentrically positioned inside polystyrene shells. The interfacial tension between the inorganic core and monomer-swollen polymer shell and the effect of swelling and phase separation have been employed to tune the morphology and structure of the composite colloids. The uniform size, anisotropic structure/shape, and the additional magnetic control make these colloidal particles ideal building blocks for the fabrication of novel functional devices and materials.
引用
收藏
页码:8974 / +
页数:3
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