Modulation of the water exchange rates in [Gd-DO3A] complex by formation of ternary complexes with carboxylate ligands

被引:49
作者
Aime, S
Botta, M
Bruce, JI
Mainero, V
Parker, D
Terreno, E
机构
[1] Univ Turin, Dipartimento Chim IFM, I-10125 Turin, Italy
[2] Univ Piemonte Orientale Amedeo Avogadro, Dipartimento Sci & Tecnol Avanzate, I-15100 Alessandria, Italy
[3] Univ Durham, Dept Chem, Durham DH1 3LE, England
[4] Bioind Pk Canavese, Lab Integrato Metodol Avanzate, I-10010 Giacosa, TO, Italy
关键词
D O I
10.1039/b007901o
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Ternary complexes of formula [Gd-DO3A-L-(H2O)] (where L is a carboxylate-containing ligand) display exchange lifetimes of the metal-coordinated water that can be modulated as a function of L.
引用
收藏
页码:115 / 116
页数:2
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