Addition of polyfluoroalkyl iodides to allyl glycidyl ether

被引：12

作者：

Bazhin, D. N. ^{[1
]}

Gorbunova, T. I. ^{[1
]}

Zapevalov, A. Ya. ^{[1
]}

Saloutin, V. I. ^{[1
]}

机构：

[1] Russian Acad Sci, Ural Branch, I Ya Postovskii Inst Organ Synth, Ekaterinburg 620041, Russia

来源：

RUSSIAN CHEMICAL BULLETIN | 2007年 / 56卷 / 08期

关键词：

glycidyl ethers; polyfluoroalkyl iodides; sodium dithionite; oxiranes; olefins; organofluorine compounds; free-radical processes;

D O I：

10.1007/s11172-007-0237-3

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Addition of polyfluoroalkyl iodides to the double bond of allyl glycidyl ether occurred under mild conditions (20 - 25 degrees C, MeCN/H2O, Na2S2O4, NaHCO3) with retention of the oxirane ring.

引用

页码：1534 / 1536

页数：3

共 24 条

[1] SYNTHESIS 3-[2F-ALKYLETHYLAMINO]-1,2-EPOXYPROPANES AND PREPARATION OF NEW MONOTAILED AND BITAILED SURFACTANTS WITH BETA-HYDROXYL GROUP [J].

ABENIN, PS ;

SZONYI, F ;

CAMBON, A .

JOURNAL OF FLUORINE CHEMISTRY, 1991, 55 (01) :1-11

[2] Synthesis, characterisation and aqueous behaviour of a one-ended perfluorocarbon-modified poly(ethylene glycol) [J].

Boschet, F ;

Branger, C ;

Margaillan, A ;

Condamine, E .

POLYMER, 2002, 43 (19) :5329-5334

[3] SYNTHESIS OF EPOXIDES AND GLYCIDYL ETHERS WITH A CHLOROFLUORINATED CHAIN [J].

BOUTEVIN, B ;

HUGON, JP ;

PIETRASANTA, Y .

JOURNAL OF FLUORINE CHEMISTRY, 1981, 17 (04) :357-374

[4] Syntheses with perfluoroalkyl radicals from perfluoroalkyl iodides. A rapid survey of synthetic possibilities with emphasis on practical applications. Part one: Alkenes, alkynes and allylic compounds [J].

Brace, NO .

JOURNAL OF FLUORINE CHEMISTRY, 1999, 93 (01) :1-25

[5] THE PREPARATION AND PROPERTIES OF SOME VINYL AND GLYCIDYL FLUOROETHERS [J].

BREY, ML ;

TARRANT, P .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1957, 79 (24) :6533-6536

[6] POLYMERS DERIVED FROM 2-PHENYL-1,1,1,3,3,3-HEXAFLUOROPROPAN-2-OL AND ITS DERIVATIVES [J].

CASSIDY, PE ;

AMINABHAVI, TM ;

REDDY, VS ;

FITCH, JW .

EUROPEAN POLYMER JOURNAL, 1995, 31 (04) :353-361

[7] RADICAL-INDUCED REACTION OF MONOIODO-PERFLUOROALKANES AND DIIODO-PERFLUOROALKANES WITH ALLYL ACETATE - TELOMER AND REARRANGED PRODUCTS, MASS-SPECTRAL DISTINGUISHING OF REGIOISOMERS [J].

CIRKVA, V ;

AMEDURI, B ;

BOUTEVIN, B ;

KVICALA, J ;

PALETA, O .

JOURNAL OF FLUORINE CHEMISTRY, 1995, 74 (01) :97-105

[8] FLUORINATED DIEPOXIDES [J].

DAMMONT, FR ;

SHARPE, LH ;

SCHONHORN, H .

JOURNAL OF POLYMER SCIENCE PART B-POLYMER LETTERS, 1965, 3 (12PB) :1021-&

[9]

GORBUNOVA TI, 1991, ZH OBSHCH KHIM+, V61, P2364

[10]

GORBUNOVA TI, 1991, ZH OBSHCH KHIM, V61, P96

← 1 2 3 →