Engineering of octacyanometalate-based coordination networks towards functionality

被引：156

作者：

Sieklucka, B ^{[1
]}

Podgajny, R ^{[1
]}

Przychodzen, P ^{[1
]}

Korzeniak, T ^{[1
]}

机构：

[1] Jagiellonian Univ, Fac Chem, PL-30060 Krakow, Poland

来源：

COORDINATION CHEMISTRY REVIEWS | 2005年 / 249卷 / 21-22期

关键词：

crystal engineering; octacyanomolybdate; octacyanotungstate; magnetic properties; cyano bridge; crystal structures;

D O I：

10.1016/j.ccr.2005.02.024

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The design and construction of new supramolecular coordination compounds based on octacyanometalate [M(CN)(8)](3-4-) (M = Mo and W) building blocks of potential utility as functional materials has received considerable attention over the recent years. The research in this field has resulted in the cyano-bridged polynuclear octacyanometalate-based molecules and polymeric coordination networks which behave like molecular magnets and photo-induced magnetic materials. This article surveys the superstructural complexity of some coordination frameworks built by multidirectional non-rigid octacyanometalate anions as linkers in self-assembly with convergent Mn(II,III), Co(III), Cu(II) and Pt(II) complexes with polyamine, diimine and Schiff-base blocking ligands. The role of intermolecular directional forces in propagation of M-CN-M' linkages into the architectures of various dimensionalities and topologies is pointed out. The network topologies are outlined and the structure/property relationship is discussed. (c) 2005 Elsevier B.V. All rights reserved.

引用

页码：2203 / 2221

页数：19

共 167 条

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