Cross-Linked Multifunctional Conjugated Polymers Prepared by In Situ Electrochemical Deposition for a Highly-Efficient Blue-Emitting and Electron-Transport Layer

被引：55

作者：

Gu, Cheng ^{[1
]}

Dong, Wenyue ^{[1
]}

Yao, Liang ^{[1
]}

Lv, Ying ^{[1
]}

Zhang, Zhongbo ^{[1
]}

Lu, Dan ^{[1
]}

Ma, Yuguang ^{[1
]}

机构：

[1] Jilin Univ, State Key Lab Supramol Struct & Mat, Changchun 130012, Peoples R China

来源：

ADVANCED MATERIALS | 2012年 / 24卷 / 18期

关键词：

electrochemical deposition; cross-linking; polymer precursor; blue-emitting PLEDs; electron-transport layer; WHITE-LIGHT EMISSION; SINGLE-POLYMER; PHOSPHONATE GROUPS; THIN-FILMS; DIODES; ELECTROLUMINESCENCE; MORPHOLOGY; COPOLYMER; DEVICES; SYSTEM;

D O I：

10.1002/adma.201200559

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An efficient and controllable approach to prepare cross-linked films from a conjugated polymer precursor by electrochemical deposition (ED) is reported for the first time. A novel polymer precursor with high solubility, high electroactivity, and electron-transport ability has been designed. The electrochemically deposited polymer film shows high thickness, smooth morphology, and high fluorescence. The single-layer pure-blue-emitting ED PLED exhibits a luminous efficiency of 3.8 cd A(-1).

引用

页码：2413 / 2417

页数：5

共 24 条

[1] Investigating work function tunable hole-injection/transport layers of electrodeposited polycarbazole network thin films [J].

Baba, A ;

Onishi, K ;

Knoll, W ;

Advincula, RC .

JOURNAL OF PHYSICAL CHEMISTRY B, 2004, 108 (49) :18949-18955

[2] Photolithographic hole-transport layer derived from electrochemical deposition of oligo(5-vinyl-2-nitrobenzyl triphenylamine-4-carboxylate) [J].

Chang, Chin-Chuan ;

Leung, Man-kit .

CHEMISTRY OF MATERIALS, 2008, 20 (18) :5816-5821

[3] Recent Progress in Polymer Solar Cells: Manipulation of Polymer: Fullerene Morphology and the Formation of Efficient Inverted Polymer Solar Cells [J].

Chen, Li-Min ;

Hong, Ziruo ;

Li, Gang ;

Yang, Yang .

ADVANCED MATERIALS, 2009, 21 (14-15) :1434-1449

[4] Functionality of Peripheral Side Chain for Enhanced Performance of Conjugated Polymer-F8BT as an Example [J].

Dong, Wenyue ;

Xue, Shanfeng ;

Lu, Ping ;

Deng, Jian ;

Zhao, Donglin ;

Gu, Cheng ;

Ma, Yuguang .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2011, 49 (21) :4549-4555

[5] Multilayer polymer light-emitting diodes: White-light emission with high efficiency [J].

Gong, X ;

Wang, S ;

Moses, D ;

Bazan, GC ;

Heeger, AJ .

ADVANCED MATERIALS, 2005, 17 (17) :2053-+

[6] Color-stable White Electroluminescence Based on a Cross-linked Network Film Prepared by Electrochemical Copolymerization [J].

Gu, Cheng ;

Fei, Teng ;

Lv, Ying ;

Feng, Tao ;

Xue, Shanfeng ;

Lu, Dan ;

Ma, Yuguang .

ADVANCED MATERIALS, 2010, 22 (24) :2702-+

[7] Electrochemical polymerization films for highly efficient electroluminescent devices and RGB color pixel [J].

Gu, Cheng ;

Fei, Teng ;

Zhang, Ming ;

Li, Chuannan ;

Lu, Dan ;

Ma, Yuguang .

ELECTROCHEMISTRY COMMUNICATIONS, 2010, 12 (04) :553-556

[8] White Electroluminescence from a Phosphonate-Functionalized Single-Polymer System with Electron-Trapping Effect [J].

Guo, Xin ;

Qin, Chuanjiang ;

Cheng, Yanxiang ;

Xie, Zhiyuan ;

Geng, Yanhou ;

Jing, Xiabin ;

Wang, Fosong ;

Wang, Lixiang .

ADVANCED MATERIALS, 2009, 21 (36) :3682-+

[9] High-efficiency white-light-emitting devices from a single polymer by mixing singlet and triplet emission [J].

Jiang, Jiaxing ;

Xu, Yunhua ;

Yang, Wei ;

Guan, Rong ;

Liu, Zhenqin ;

Zhen, Hongyu ;

Cao, Yong .

ADVANCED MATERIALS, 2006, 18 (13) :1769-+

[10] The Simple Way to Solution-Processed Multilayer OLEDs - Layered Block-Copolymer Networks by Living Cationic Polymerization [J].

Koehnen, Anne ;

Riegel, Nina ;

Kremer, Jonas H. -W. M. ;

Lademann, Hans ;

Mueller, David C. ;

Meerholz, Klaus .

ADVANCED MATERIALS, 2009, 21 (08) :879-+

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